Implementation of orbitrap mass spectrometry for improved GC-MS target analysis in lithium ion battery electrolytes
| العنوان: | Implementation of orbitrap mass spectrometry for improved GC-MS target analysis in lithium ion battery electrolytes |
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| المؤلفون: | Christoph Peschel, Fabian Horsthemke, Martin Winter, Sascha Nowak |
| المصدر: | MethodsX MethodsX, Vol 9, Iss, Pp 101621-(2022) |
| بيانات النشر: | Elsevier BV, 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Science, GC-HRMS, Clinical Biochemistry, EI, electron ionization, Target analysis, BMC, n-butyl methyl carbonate, sBEC, sec-butyl ethyl carbonate, Method Article, LIB, lithium ion battery, Orbitrap mass spectrometry, EPC, ethyl propyl carbonate, BEC, n-butyl ethyl carbonate, MPC, methyl propyl carbonate, SQ, single quadrupole, Lithium ion battery electrolytes, EIC, extracted ion chromatogram, Target analysis via GC-HRMS of lithium ion battery electrolyte decomposition, HRMS, high resolution mass spectrometry, Medical Laboratory Technology, GC-MS, gas chromatography – mass spectrometry, FWHM, full width at half maximum, sBMC, sec-butyl methyl carbonate, SPME, solid phase microextraction |
| الوصف: | The implementation of orbitrap mass spectrometry for target analysis of volatile species in aged lithium-ion batteries was performed in a case study on butyl carbonates. In comparison to previously applied single quadrupole-based methods, major improvements were obtained.•Sensitivity was improved by effectively background free extracted ion chromatograms of identified marker fragment ions.•Typical isobaric interferences of typical carbonate fragment ions e.g. caused by column bleeding were identified and false positive identification avoided.•Analysis of isotope labeled electrolytes was optimized regarding mass spectrometric data reliability with mass accuracies 100,000. Graphical abstract Image, graphical abstract |
| تدمد: | 2215-0161 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::36afaecbddb047bb37f6f9acd8e58a5dTest https://doi.org/10.1016/j.mex.2022.101621Test |
| حقوق: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....36afaecbddb047bb37f6f9acd8e58a5d |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 22150161 |
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