التفاصيل البيبلوغرافية
| العنوان: |
Pinhole-Free Shell-Isolated Nanoparticle Enhanced Raman Spectroscopy for Interference-Free Probing of Electrochemical Reactions |
| المؤلفون: |
N. K. Murugasenapathi (11171514), K. A. Esther Jebakumari (11171517), S. Jamal Mohamed (11171520), K. Giribabu (11171523), Tamilarasan Palanisamy (11171526) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biochemistry, Medicine, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, interference-free enhancement, chemical changes, Nile Blue, pinhole-free silica layer, electrocatalytic reactions, redox reaction, analyte, Raman signal enhancement, reaction mechanisms, Surface Enhanced Raman Scattering, nonplasmonic surfaces, silver nanostructures, electrochemical method, spectroelectrochemical data, Pinhole-Free Shell-Isolated Nanopar., pinhole-free silica-coated silver n., chemical reduction method, carbon surface, electron transfer, Raman signals, electrode surface, plasmonic SERS substrates, reaction mechanism, Electrochemical Reactions |
| الوصف: |
Investigating the behavior of analytes at the electrode surface is crucial in understanding the electrochemical and electrocatalytic reactions. Although Surface Enhanced Raman Scattering (SERS) is sensitive to minor chemical changes in the analyte, it is not widely used to study the reaction mechanisms on nonplasmonic surfaces because of the interference from plasmonic SERS substrates. In this study, we have investigated the redox reaction of Nile Blue A on a glassy carbon surface using pinhole-free silica-coated silver nanoparticles for Raman signal enhancement. The silver nanostructures were synthesized by a chemical reduction method, and the quality of the silica layer was confirmed using microscopic and electrochemical method. The in situ spectroelectrochemical data reveals the catalytic interference from silver which considerably alters the native reaction mechanism. The pinhole-free silica layer prevents the hot electron transfer and yields an interference-free enhancement to the Raman signals. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/Pinhole-Free_Shell-Isolated_Nanoparticle_Enhanced_Raman_Spectroscopy_for_Interference-Free_Probing_of_Electrochemical_Reactions/15035649Test |
| DOI: |
10.1021/acs.jpclett.1c01768.s001 |
| الإتاحة: |
https://doi.org/10.1021/acs.jpclett.1c01768.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.976B2611 |
| قاعدة البيانات: |
BASE |
