التفاصيل البيبلوغرافية
| العنوان: |
Cross-Validation of the Remarkably High Surface Oxygen Exchange Kinetics of PrBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ : A Combined Thin-Film Mass Relaxation and Bulk Electrical Conductivity Relaxation Study |
| المؤلفون: |
Xin Qian, Sossina M. Haile |
| سنة النشر: |
1753 |
| المجموعة: |
Smithsonian Institution: Figshare |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Space Science, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, surface microstructural features, oxygen partial pressure, oxygen kinetic properties, material widely used, bulk sample reveals, bulk bar sample, 600 ° c, overall relaxation behavior, electrical conductivity relaxation, 74 ± 0, 2 × 10, film mass relaxation, power law dependence, phase boundary oxidation, δ , 2 , 0 × 10, double perovskite prba, 5 , mass relaxation, , relaxation process, p <, k < |
| الوصف: |
In this work, we measure the oxygen kinetic properties of double perovskite PrBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ (PBSCF), a material widely used as the air electrode in solid oxide electrochemical cells, by mass relaxation (MR) and electrical conductivity relaxation (ECR) experiments. MR studies are carried out using thin films deposited on a gallium phosphate piezocrystal microbalance, and ECR studies are performed using a bulk bar sample with 97% theoretical density. Measurements are performed at 600 °C over the temperature oxygen partial pressure range from 10 –4 to 0.21 atm. Despite the differences in experimental formats and surface microstructural features, the k s values extracted from the two methods are found to be in good agreement with one another. The rate constant is found to increase with oxygen partial pressure with a power law dependence, rising from 1.0 × 10 –6 cm/s at 3.2 × 10 –4 atm to 1.2 × 10 –4 cm/s at 0.24 atm, as averaged over the oxidation and reduction directions. The rates in the oxidation direction are observed to be slightly higher than those in the reduction direction for a given pair of p O 2 values, suggesting that the final p O 2 value controls the overall relaxation behavior. The power law exponent describing the dependence of k s on p O 2 is found to be 0.74 ± 0.01. The ECR study of the bulk sample reveals that even with a diffusion length of 1.8 mm, the relaxation process is largely free of diffusion limitations, indicating that PBSCF has the high bulk transport properties required for a double-phase boundary oxidation/reduction pathway. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/Cross-Validation_of_the_Remarkably_High_Surface_Oxygen_Exchange_Kinetics_of_PrBa_sub_0_5_sub_Sr_sub_0_5_sub_Co_sub_1_5_sub_Fe_sub_0_5_sub_O_sub_5_sub_A_Combined_Thin-Film_Mass_Relaxation_and_Bulk_Electrical_Conductivity_Relaxation_Study/25388108Test |
| DOI: |
10.1021/acsami.3c18574.s001 |
| الإتاحة: |
https://doi.org/10.1021/acsami.3c18574.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.26044DFA |
| قاعدة البيانات: |
BASE |
