التفاصيل البيبلوغرافية
| العنوان: |
One-Pot and Unsymmetrical Bis-Allylation of Malononitrile with Conjugated Dienes and Allylic Alcohols |
| المؤلفون: |
Wenxiu Gao (2569912), Dong Zhang (73558), Xiaoyu Zhang (62901), Xinying Cai (6742988), Peizhong Xie (1457611), Teck-Peng Loh (1433638) |
| سنة النشر: |
2022 |
| مصطلحات موضوعية: |
Biochemistry, Medicine, Genetics, Pharmacology, Biotechnology, Ecology, Science Policy, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, catalytic system suppressed, ca catalytic system, competitive symmetrical bis, desired unsymmetrical bis, selecting conjugated dienes, unsymmetrical bis, conjugated dienes, wide range, tolerated well, high efficiency, high chemoselectivity, diverse 1, allylic reagents, allylic alcohols |
| الوصف: |
A Pd/Ca catalytic system to promote the unsymmetrical bis-allylation of malononitrile was developed by selecting conjugated dienes and allylic alcohols as allylic reagents. This catalytic system suppressed the competitive symmetrical bis-allylation process and guaranteed the desired unsymmetrical bis-allylation with high chemoselectivity. A wide range of conjugated dienes and allylic alcohols were tolerated well in this transformation, and diverse 1,6-dienes were obtained with high efficiency. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/One-Pot_and_Unsymmetrical_Bis-Allylation_of_Malononitrile_with_Conjugated_Dienes_and_Allylic_Alcohols/21732237Test |
| DOI: |
10.1021/acs.orglett.2c03405.s001 |
| الإتاحة: |
https://doi.org/10.1021/acs.orglett.2c03405.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.4112B95C |
| قاعدة البيانات: |
BASE |
