التفاصيل البيبلوغرافية
| العنوان: |
Ruthenium-Catalyzed Cross-Coupling of Ketones as an Alkenyl Electrophile with Organoborons via Cleavage of Alkenyl C–N Bonds of in Situ Generated Enamines |
| المؤلفون: |
Yuya Kogure (14248374), Satoshi Ueno (731209) |
| سنة النشر: |
1753 |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Microbiology, Molecular Biology, Biotechnology, Immunology, Developmental Biology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, organoborons via cleavage, reaction proceeds via, situ generated enamines, enamines generated, catalytic cleavage, organoboronic esters, catalyzed cross, alkenyl electrophile |
| الوصف: |
A ruthenium-catalyzed cross-coupling reaction of ketones with organoboronic esters was developed. In this reaction, ketones possessing a pyridine-directing group directly functions as an alkenyl electrophile for coupling with organoboronates in the presence of pyrrolidine and a ruthenium catalyst. This reaction proceeds via the catalytic cleavage of the alkenyl carbon–nitrogen bond in the enamines generated in situ from ketones with pyrrolidine, benzylamine, or isoindoline. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/Ruthenium-Catalyzed_Cross-Coupling_of_Ketones_as_an_Alkenyl_Electrophile_with_Organoborons_via_Cleavage_of_Alkenyl_C_N_Bonds_of_in_Situ_Generated_Enamines/21713880Test |
| DOI: |
10.1021/acs.orglett.2c03765.s001 |
| الإتاحة: |
https://doi.org/10.1021/acs.orglett.2c03765.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.F36944E7 |
| قاعدة البيانات: |
BASE |
