التفاصيل البيبلوغرافية
| العنوان: |
Polymerization-Induced Self-Assembly Driven by the Synergistic Effects of Aromatic and Solvophobic Interactions |
| المؤلفون: |
Xiao-Fei Xu (6415703), Ren-Man Zhu (10218923), Cai-Yuan Pan (1836658), Ye-Zi You (1442518), Wen-Jian Zhang (1836655), Chun-Yan Hong (1588348) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Neuroscience, Pharmacology, Evolutionary Biology, Virology, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, solvophobic interactions, Solvophobic Interactions Polymeriza., sub -100 nm, vesicle, RAFT dispersion polymerization, PISA, CMA |
| الوصف: |
Polymerization-induced self-assembly (PISA) has been established as an efficient method to fabricate polymeric vesicles. In most PISA cases, the formation of vesicles is solely driven by the solvophobic interactions. Besides solvophobic effects, many other noncovalent interactions can also drive/influence self-assembly of block copolymers. In this work, PISA driven by the synergistic effects of solvophobic and aromatic interactions is investigated. 7-(2-Methacryloyloxyethoxy)-4-methylcoumarin (CMA) is selected as a model monomer for RAFT dispersion polymerization to fabricate vesicles with both solvophobic and aromatic interactions existing in the membrane-forming blocks. Controlling vesicular size in the range of sub-100 nm to micrometer in PISA is realized by copolymerization of CMA with three different comonomers (aromatic or not) in various proportions to adjust the intermolecular interactions. Moreover, polymeric tubes with adjustable aspect ratios (from about 2 to 20) are produced by applying the cooperativity of aromatic and solvophobic interactions. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/Polymerization-Induced_Self-Assembly_Driven_by_the_Synergistic_Effects_of_Aromatic_and_Solvophobic_Interactions/14141792Test |
| DOI: |
10.1021/acs.macromol.0c02882.s001 |
| الإتاحة: |
https://doi.org/10.1021/acs.macromol.0c02882.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.E4BC78B5 |
| قاعدة البيانات: |
BASE |
