التفاصيل البيبلوغرافية
| العنوان: |
STUDYING THE ELECTRONIC STRUCTURE OF TRINUCLEAR MOLYBDENUM CLUSTER SULFIDES WITH {Mo3S4} AND {Mo3S7} CORES BY X-RAY SPECTROSCOPY. |
| المؤلفون: |
Fedorenko, A. D., Semushkina, G. I., Peregudova, N. N., Lavrukhina, S. A., Gushchin, A. L., Fomenko, Ya. S., Sokolov, M. N., Gusel′nikov, A. V., Kalinkin, A. V., Nikolenko, A. D., Ivlyushkin, D. V., Zavertkin, P. S., Mazalov, L. N. |
| المصدر: |
Journal of Structural Chemistry; Jun2021, Vol. 62 Issue 6, p853-864, 12p |
| مصطلحات موضوعية: |
X-ray absorption near edge structure, MOLYBDENUM sulfides, FRONTIER orbitals, X-ray spectroscopy, ELECTRONIC structure |
| مستخلص: |
A comprehensive study of the electronic structure of trinuclear molybdenum complexes (NH4)2[Mo3S13] and [Mo3S7(dtc)3]Br with cluster core {Mo3S7} and [Mo3S4(tu)8H2O]Cl4 complexes with cluster core {Mo3S4} is conducted by X-ray emission spectroscopy (XES), X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge structure (XANES) spectroscopy, and quantum chemistry methods. Data were obtained on the partial atomic composition of the highest occupied molecular orbitals and unoccupied molecular orbitals and the nature of atomic interactions within cluster cores. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
