H2S-responsive zwitterionic hydrogel as a self–healing agent for plugging microcracks in oil-well cement.

التفاصيل البيبلوغرافية
العنوان: H2S-responsive zwitterionic hydrogel as a self–healing agent for plugging microcracks in oil-well cement.
المؤلفون: Huang, Xiaona, Zhang, Hao, Wang, Xuguang, Yang, Xiutian, Lin, Rongzhuang, Zhang, Fan, Liu, Ying, Xu, Kun, Zhou, Chao, Wang, Pixin
المصدر: Journal of Industrial & Engineering Chemistry; Nov2023, Vol. 127, p523-532, 10p
مصطلحات موضوعية: SELF-healing materials, CEMENT slurry, MICROCRACKS, CHEMICAL processes, CEMENT, SOLUTION (Chemistry)
مستخلص: [Display omitted] During cementing construction, H 2 S gas leak from micro-cracks of cement ring or cementing interface, seriously damaging wellbore integrity and shortening the life of wells. Therefore, microcrack self-healing cement technology is of great significance for oil wells to maintain the durability of cement rings and adapt to complex underground environments. Herein, acrylamide (AM), acrylonitrile (AN) and N-vinylformamide (NVF) were used as functional monomers, and laponite was added to prepare Laponite-poly(acrylamide-acrylonitrile-n-vinylformamide) nanocomposite hydrogel (L-PMAN) with excellent mechanical strength as micro-crack repair agent for gas-triggered cementing cement sheath. Considering the difference of chemical environment in the process of wellbore cement slurry sealing and subsequent micro-fracture plugging, different structural units were selected to design amphoteric structure. The construction of zwitterionic structure makes it exhibit excellent swelling behavior in salt solution while maintaining 80% of the original mechanical strength. More importantly, after adding L-PMAN powder,cement stone (C 1) can achieve good repair of microcracks under the trigger of H 2 S within 3 days, and the maximum gas breakthrough pressure can reach 2.5 MPa, indicating the great potentials of the L-PMAN for plugging microcracks in cement sheath. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Supplemental Index
الوصف
تدمد:1226086X
DOI:10.1016/j.jiec.2023.06.056