دورية أكاديمية

Phosphate minerals in LL chondrites: A record of the action of fluids during metamorphism on ordinary chondrite parent bodies

التفاصيل البيبلوغرافية
العنوان: Phosphate minerals in LL chondrites: A record of the action of fluids during metamorphism on ordinary chondrite parent bodies
المؤلفون: Jones, Rhian H., McCubbin, Francis M., Dreeland, Linda, Guan, Yunbin, Burger, Paul V., Shearer, Charles K.
المصدر: Geochimica et Cosmochimica Acta, 132, 120-140, (2014-05-01)
بيانات النشر: Elsevier
سنة النشر: 2014
المجموعة: Caltech Authors (California Institute of Technology)
الوصف: Ordinary chondrites contain two phosphate minerals, merrillite and chlorapatite, both of which are secondary minerals that developed in response to metamorphism on the chondrite parent bodies. We have studied the phosphate mineralogy of four LL chondrites, of petrologic types 3.9–6, in order to determine the petrogenesis of the two minerals and interpret the conditions under which they formed. Characterization of merrillite and apatite includes textural observations, mineral compositions determined by electron probe microanalysis, and ion microprobe analyses of trace element and volatile anion elemental abundances. Initial formation of phosphate minerals during mild metamorphism, to petrologic type 4 conditions, resulted in oxidation of P that was originally incorporated in metal, and growth of merrillite as inclusions within metal grains. Subsequent development of both phosphate minerals occurred in response to diffusional equilibration, possible precipitation from fluids as well as replacement reactions resulting from interactions with fluids. Porosity and vein-filling textures in both merrillite and chlorapatite, as well as textures indicating replacement of merrillite by chlorapatite, support a model in which fluid played a significant role and suggest an interface-coupled dissolution–reprecipitation mechanism during metasomatism. Some associations of phosphate minerals with chromite-plagioclase assemblages suggest that phosphate minerals could also be related to impact processes, either as precipitation from an impact melt or as a result of interactions with a fluid or vapor derived from an impact melt. Fluid compositions may have been water-bearing initially, at low temperatures of metamorphism, but later evolved to become halogen-rich and very dry. Late-stage halogen-rich fluids that dominated during cooling of LL chondrite material may have been derived from vaporization of partial melts in the interior of the parent body. Overall, the LL chondrite parent body underwent a complex chemical evolution, ...
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
العلاقة: https://doi.org/10.1016/j.gca.2014.01.027Test; oai:authors.library.caltech.edu:g5568-y1282; eprintid:45917; resolverid:CaltechAUTHORS:20140527-102509954
DOI: 10.1016/j.gca.2014.01.027
الإتاحة: https://doi.org/10.1016/j.gca.2014.01.027Test
حقوق: info:eu-repo/semantics/openAccess ; Other
رقم الانضمام: edsbas.7D407F1C
قاعدة البيانات: BASE