التفاصيل البيبلوغرافية
| العنوان: |
One-Pot Synthesis of 1,5-Diketones under a Transition-Metal-Free Condition: Application in the Synthesis of 2,4,6-Triaryl Pyridine Derivatives |
| المؤلفون: |
Kesatebrhan Haile Asressu (10277062), Chieh-Kai Chan (2936862), Cheng-Chung Wang (1735783) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biochemistry, Cell Biology, Genetics, Molecular Biology, Biotechnology, Ecology, Computational Biology, Chemical Sciences not elsewhere classified, nitrogen source, transition-metal-free condition, Claisen, Michael addition reaction, Application, Diketone, Derivative, ammonium acetate, base employment, aryl aldehydes, additive, substrate scope, One-Pot Synthesis, strategy, Pyridine, method, preparation, catalyst-free system, material, X-ray single-crystal diffraction an., reagent, cost-effectiveness |
| الوصف: |
We developed a facile and green one-pot synthetic method for substituted 1,3,5-triaryl-1,5-diketones by Claisen–Schmidt condensation following Michael addition reaction of aryl ketones and aryl aldehydes under a transition-metal-free condition. This convenient one-pot synthetic strategy has several advantages, including being transition-metal-free, having no extra additives or reagents, having a broad substrate scope, having a high isolated yield, having a minimum amount of base employment, having a shorter reaction time, use of cheap starting materials, cost-effectiveness, and being environment friendly. Some of the chemical structures of 1,5-diketones were confirmed by X-ray single-crystal diffraction analysis. The application of 1,5-diketones was demonstrated in the preparation of 2,4,6-triaryl pyridine derivatives under a catalyst-free system using ammonium acetate as a nitrogen source. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/One-Pot_Synthesis_of_1_5-Diketones_under_a_Transition-Metal-Free_Condition_Application_in_the_Synthesis_of_2_4_6-Triaryl_Pyridine_Derivatives/14188213Test |
| DOI: |
10.1021/acsomega.0c05328.s002 |
| الإتاحة: |
https://doi.org/10.1021/acsomega.0c05328.s002Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.E551A24B |
| قاعدة البيانات: |
BASE |
