دورية أكاديمية
A Genuine Trivalent Bis-Acylphosphide (BAP) Complex of Uranium
| العنوان: | A Genuine Trivalent Bis-Acylphosphide (BAP) Complex of Uranium |
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| المؤلفون: | Hochholzer, Jakob, Waldschmidt, Pablo, Heinemann, Frank W., Grützmacher, Hansjörg, id_orcid:0 000-0002-1531-8906, Meyer, Karsten |
| المصدر: | European Journal of Inorganic Chemistry, 27 (6) |
| بيانات النشر: | Wiley-VCH |
| سنة النشر: | 2024 |
| المجموعة: | ETH Zürich Research Collection |
| مصطلحات موضوعية: | Uranium Complexes, Bisacylphosphide BAP, Ligands, Spectroscopy, Magnetism |
| الوصف: | The genuine trivalent uranium complex, K[UIII(mesBAP)4], employing four bidentate bis(2,4,6-trimethylbenzoyl)phosphide (mesBAP) chelating ligands, is reported and obtained by the reduction of the literature-known tetravalent analog [UIV(mesBAP)4]. Hence, the bis(acyl)phosphide mesBAP ligand allowed to establish a fully reversible redox couple with uranium in the oxidation states +III and +IV. In both complexes [U(mesBAP)4]0/-, the uranium ions are coordinated to four mesBAP ligands in a square antiprismatic geometry. All new compounds have been characterized by single-crystal XRD analysis, 1H and 31P NMR, and UV/Vis/NIR electronic absorption spectroscopy, as well as SQUID magnetization and electrochemical measurements, and CW X-band EPR in the case of the trivalent complex. ; ISSN:1434-1948 ; ISSN:1099-0682 |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/application/pdf |
| اللغة: | English |
| العلاقة: | info:eu-repo/semantics/altIdentifier/wos/001146502500001; http://hdl.handle.net/20.500.11850/656433Test |
| DOI: | 10.3929/ethz-b-000656433 |
| الإتاحة: | https://doi.org/20.500.11850/656433Test https://doi.org/10.3929/ethz-b-000656433Test https://doi.org/10.1002/ejic.202300592Test https://hdl.handle.net/20.500.11850/656433Test |
| حقوق: | info:eu-repo/semantics/openAccess ; http://creativecommons.org/licenses/by-nc-nd/4.0Test/ ; Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International |
| رقم الانضمام: | edsbas.15D44E64 |
| قاعدة البيانات: | BASE |
| DOI: | 10.3929/ethz-b-000656433 |
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