دورية
Solid and Solution State Structures of a Reversible Molecular Oxygen-Carrying Molybdenum Porphyrin Dioxygen Complex
| العنوان: | Solid and Solution State Structures of a Reversible Molecular Oxygen-Carrying Molybdenum Porphyrin Dioxygen Complex |
|---|---|
| المؤلفون: | Fujihara, Tetsuaki, Rees, Nicholas H, Umakoshi, Keisuke, Tachibana, Junichi, Sasaki, Yoichi, McFarlane, William, Imamura, Taira |
| المصدر: | Chemistry Letters; February 2000, Vol. 29 Issue: 2 p102-103, 2p |
| مستخلص: | The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cisconformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion of the porphyrin ring is retained in solution. |
| قاعدة البيانات: | Supplemental Index |
| تدمد: | 03667022 13480715 |
|---|---|
| DOI: | 10.1246/cl.2000.102 |