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المؤلفون: Saeed Sepasi, Silas Toledo, Jonathan Kobayashi, Leon R. Roose, Marc M. Matsuura, Quynh T. Tran
المصدر: Renewable Energy. 202:581-588
مصطلحات موضوعية: Renewable Energy, Sustainability and the Environment
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_________::e2d702baadfe2c4aa810dbfbe269e2daTest
https://doi.org/10.1016/j.renene.2022.11.114Test -
2دورية أكاديمية
المؤلفون: Jurriën W. Collet, Thomas R. Roose, Bram Weijers, Bert U. W. Maes, Eelco Ruijter, Romano V. A. Orru
المصدر: Molecules; Volume 25; Issue 21; Pages: 4906
مصطلحات موضوعية: isocyanides, palladium, insertion reactions, heterocycles, catalysis
جغرافية الموضوع: agris
الوصف: Isocyanides have long been known as versatile chemical reagents in organic synthesis. Their ambivalent nature also allows them to function as a CO-substitute in palladium-catalyzed cross couplings. Over the past decades, isocyanides have emerged as practical and versatile C1 building blocks, whose inherent N-substitution allows for the rapid incorporation of nitrogeneous fragments in a wide variety of products. Recent developments in palladium catalyzed isocyanide insertion reactions have significantly expanded the scope and applicability of these imidoylative cross-couplings. This review highlights the advances made in this field over the past eight years.
وصف الملف: application/pdf
العلاقة: Organic Chemistry; https://dx.doi.org/10.3390/molecules25214906Test
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المؤلفون: Thomas R. Roose, H. Daniel Preschel, Helena Mayo Tejedor, Jasper C. Roozee, Trevor A. Hamlin, Bert U. W. Maes, Eelco Ruijter, Romano V. A. Orru
المساهمون: AMIBM, RS: FSE AMIBM, Organic Chemistry, AIMMS, Theoretical Chemistry, Chemistry and Pharmaceutical Sciences
المصدر: Chemistry: a European journal. Wiley-VCH Verlag
Chemistry-A European Journal, 29(9):e202203074. Wiley-VCH Verlag
Chemistry: a European journal
Roose, T R, Preschel, H D, Mayo Tejedor, H, Roozee, J C, Hamlin, T A, Maes, B U W, Ruijter, E & Orru, R V A 2023, ' Iron-Catalysed Carbene Transfer to Isocyanides as a Platform for Heterocycle Synthesis ', Chemistry-A European Journal, vol. 29, no. 9, e202203074 . https://doi.org/10.1002/chem.202203074Testمصطلحات موضوعية: isocyanide, Organic Chemistry, Carbene transfer, General Chemistry, Hieber anion, Catalysis, carbene transfer, Ketenimine, Chemistry, Isocyanide, ketenimine, Iron catalysis, SDG 6 - Clean Water and Sanitation, iron catalysis
الوصف: An iron-catalysed carbene transfer reaction of diazo compounds to isocyanides has been developed. The resulting ketenimines are trapped in situ with various bisnucleophiles to access a range of densely functionalized heterocycles (pyrimidinones, dihydropyrazolones, 1H-tetrazoles) in a one-pot process. The electron-rich Hieber anion ([Fe(CO) 3NO] −) facilitates efficient catalytic carbene transfer from acceptor-type α-diazo carbonyl compounds to isocyanides, providing a cost-efficient and benign alternative to similar noble metal-catalysed processes. Based on DFT calculations a plausible reaction mechanism for activation of the α-diazo carbonyl carbene precursor and ketenimine formation is provided.
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::33d578828a51daa1250d910a7c4c6ef4Test
https://doi.org/10.1002/chem.202203074Test -
4دورية أكاديمية
المؤلفون: Saeed Sepasi, Leon R. Roose, Marc M. Matsuura
المصدر: Energies, Vol 8, Iss 6, Pp 5217-5233 (2015)
مصطلحات موضوعية: Li-ion battery, aged cell, state of charge, extended Kalman filter, fuzzy, Technology
الوصف: As the world moves toward greenhouse gas reduction, there is increasingly active work around Li-ion chemistry-based batteries as an energy source for electric vehicles (EVs), hybrid electric vehicles (HEVs) and smart grids. In these applications, the battery management system (BMS) requires an accurate online estimation of the state of charge (SOC) in a battery pack. This estimation is difficult, especially after substantial battery aging. In order to address this problem, this paper utilizes SOC estimation of Li-ion battery packs using a fuzzy-improved extended Kalman filter (fuzzy-IEKF) for Li-ion cells, regardless of their age. The proposed approach introduces a fuzzy method with a new class and associated membership function that determines an approximate initial value applied to SOC estimation. Subsequently, the EKF method is used by considering the single unit model for the battery pack to estimate the SOC for following periods of battery use. This approach uses an adaptive model algorithm to update the model for each single cell in the battery pack. To verify the accuracy of the estimation method, tests are done on a LiFePO4 aged battery pack consisting of 120 cells connected in series with a nominal voltage of 432 V.
وصف الملف: electronic resource
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المؤلفون: T. R. Roose, D. S. Verdoorn, P. Mampuys, E. Ruijter, B. U. W. Maes, R. V. A. Orru
المصدر: Roose, T R, Verdoorn, D S, Mampuys, P, Ruijter, E, Maes, B U W & Orru, R V A 2022, ' Transition metal-catalysed carbene-and nitrene transfer to carbon monoxide and isocyanides ', Chemical Society Reviews, vol. 51, no. 14, pp. 5842-5877 . https://doi.org/10.1039/d1cs00305dTest
Chemical Society reviewsمصطلحات موضوعية: Carbon Monoxide, Cyanides, PALLADIUM, C-H ACTIVATION, CARBONYLATION REACTIONS, General Chemistry, ORGANIC-SYNTHESIS, COBALT-CARBENE, Chemistry, 3-COMPONENT REACTION, DIAZO-COMPOUNDS, Transition Elements, Imines, SULFONYL AZIDES, MIGRATORY INSERTION, Methane, INSERTION REACTIONS
الوصف: Transition metal-catalysed carbene- and nitrene transfer to the C1-building blocks carbon monoxide and isocyanides provides heteroallenes (i.e. ketenes, isocyanates, ketenimines and carbodiimides). These are versatile and reactive compounds allowing in situ transformation towards numerous functional groups and organic compounds, including heterocycles. Both one-pot and tandem processes have been developed providing valuable synthetic methods for the organic chemistry toolbox. This review discusses all known transition metal-catalysed carbene- and nitrene transfer reactions towards carbon monoxide and isocyanides and in situ transformation of the heteroallenes hereby obtained, with a special focus on the general mechanistic considerations.
وصف الملف: application/pdf
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f245a2b84bc2da26c8f1848040ed0ba5Test
https://research.vu.nl/en/publications/f23069b8-b83c-44ad-8e91-794f1dbdd1f0Test -
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المؤلفون: Eric R. Roose
المصدر: Routledge Handbook of Islam in the West ISBN: 9780429265860
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_________::dd4b450319034ce74a7a1632b5bd6ee6Test
https://doi.org/10.4324/9780429265860-36Test -
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المؤلفون: Eelco Ruijter, Romano V. A. Orru, Pieter Mampuys, Thomas R. Roose, Jurriën W. Collet, Bénédicte Morel, Hung-Chien Lin, Bert U. W. Maes
المساهمون: AIMMS, Organic Chemistry
المصدر: Organic Letters
Organic letters, 22(3), 914-919. American Chemical Society
Organic letters
Collet, J W, Morel, B, Lin, H C, Roose, T R, Mampuys, P, Orru, R V A, Ruijter, E & Maes, B U W 2020, ' Synthesis of Densely Functionalized Pyrimidouracils by Nickel(II)-Catalyzed Isocyanide Insertion ', Organic letters, vol. 22, no. 3, pp. 914-919 . https://doi.org/10.1021/acs.orglett.9b04387Testمصطلحات موضوعية: Letter, 010405 organic chemistry, Chemistry, Isocyanide, Organic Chemistry, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, Biochemistry, Combinatorial chemistry, Moderate temperature, 0104 chemical sciences, Catalysis, Solvent, chemistry.chemical_compound, Nickel, Yield (chemistry), Air atmosphere, Physical and Theoretical Chemistry, SDG 6 - Clean Water and Sanitation, Amination
الوصف: A robust nickel-catalyzed oxidative isocyanide insertion/C-H amination by reaction of readily available N-uracil-amidines with isocyanides affording polysubstituted pyrimidouracils has been reported. The reaction proceeds in moderate to quantitative yield, under mild conditions (i.e., green solvent, air atmosphere, moderate temperature). The broad range of structurally diverse isocyanides and N-uracil-amidines that are tolerated make this method an interesting alternative to the currently available procedures toward pyrimidouracils.
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fcc919c4d40a95f1d8ae16997138abbfTest
https://doi.org/10.1021/acs.orglett.9b04387Test -
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المصدر: Collet, J W, Roose, T R, Ruijter, E, Maes, B U W & Orru, R V A 2020, ' Base Metal Catalyzed Isocyanide Insertions ', Angewandte Chemie. International Edition, vol. 59, no. 2, pp. 540-558 . https://doi.org/10.1002/anie.201905838Test
Angewandte Chemie: international edition in Englishمصطلحات موضوعية: 010405 organic chemistry, C building blocks, Isocyanide, General Medicine, General Chemistry, imidoylation, 010402 general chemistry, 01 natural sciences, Combinatorial chemistry, Catalysis, 0104 chemical sciences, Chemistry, isocyanides, chemistry.chemical_compound, chemistry, Transition metal, Nucleophile, Electrophile, Functional group, synthetic methods, Moiety, Organometallic chemistry, base metal catalysis
الوصف: Isocyanides are diverse C1 building blocks considering their potential to react with nucleophiles, electrophiles, and radicals. Therefore, perhaps not surprisingly, isocyanides are highly valuable as inputs for multicomponent reactions (MCRs) and other one-pot cascade processes. In the field of organometallic chemistry, isocyanides typically serve as ligands for transition metals. The coordination of isocyanides to metal centers alters the electronic distribution of the isocyano moiety, and reaction pathways can therefore be accessed that are not possible in the absence of the metal. The tunable reactivity of the isocyanide functional group by transition metals has evolved into numerous useful applications. Especially palladium-catalyzed isocyanide insertion processes have emerged as powerful reactions in the past decade. However, reports on the use of earth-abundant and cheap base metals in these types of transformations are scarce and have received far less attention. In this Minireview, we focus on these emerging base metal catalyzed reactions and highlight their potential in synthetic organic chemistry. Although mechanistic studies are still scarce, we discuss distinct proposed catalytic cycles and categorize the literature according to 1) the (hetero)atom bound to and 2) the type of bonding with the transition metal in which the (formal) insertion occurs.
وصف الملف: application/pdf
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::30a803eff3405a842d7de1a9d1475417Test
https://doi.org/10.1002/anie.201905838Test -
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المؤلفون: Kevin L. Davies, Quynh T. Tran, Leon R. Roose
المصدر: 2021 IEEE/IAS 57th Industrial and Commercial Power Systems Technical Conference (I&CPS).
مصطلحات موضوعية: 010302 applied physics, Measure (data warehouse), Service (systems architecture), Test data generation, business.industry, Computer science, Deep learning, 020206 networking & telecommunications, 02 engineering and technology, Machine learning, computer.software_genre, 01 natural sciences, Fuzzy logic, 0103 physical sciences, Scalability, 0202 electrical engineering, electronic engineering, information engineering, Feature (machine learning), Artificial intelligence, business, computer, Transformer (machine learning model)
الوصف: This paper proposed a low-cost method to build the machine learning training dataset for assessing service transformer health by using fuzzy logic method. The training dataset is tested on a stimulated 50kVA server transformer. The monitoring data is collected from the real-time energy monitoring device which is installed near the transformer to measure ambient temperature, current, and voltage. The condition of transformer is evaluated by using Support Vector Machine algorithm. The data generation proposed in this paper has high feature continuity and good scalability that can be used as a training data for machine learning, deep learning models.
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_________::5932704dd8e095473182752cf1ee5002Test
https://doi.org/10.1109/icps51807.2021.9416618Test -
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المؤلفون: Reza Roofegari nejad, Nan Xue, Shahrzad Mahdavi, Zhihua Qu, Ivelisse Rivera, Sudipta Chakraborty, Wei Sun, Inalvis Alvarez Fernandez, Staci T. Sadoyama, Muenz Ulrich, Jing Wang, Xinyang Zhou, Ying Xu, Aleksandar Dimitrovski, Leon R. Roose, Yan Chen
مصطلحات موضوعية: Computer science, Distributed computing, Penetration (warfare), Scalability
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_________::beb41a80a495ab0d778cb1307c5b9269Test
https://doi.org/10.2172/1818384Test
النص الكامل