Improved Low-Temperature Performance of Li-Ion Cells Using New Electrolytes

التفاصيل البيبلوغرافية
العنوان: Improved Low-Temperature Performance of Li-Ion Cells Using New Electrolytes
المؤلفون: Buga, Ratnakumar V., Gozdz, Antoni S., Mani, Suresh, Smart, Marshall C.
المصدر: CASI
سنة النشر: 2010
المجموعة: NASA Technical Reports Server (NTRS)
مصطلحات موضوعية: Man/System Technology and Life Support
جغرافية الموضوع: Unclassified, Unlimited, Publicly available
الوصف: As part of the continuing efforts to develop advanced electrolytes to improve the performance of lithium-ion cells, especially at low temperatures, a number of electrolyte formulations have been developed that result in improved low-temperature performance (down to 60 C) of 26650 A123Systems commercial lithium-ion cells. The cell type/design, in which the new technology has been demonstrated, has found wide application in the commercial sector (i.e., these cells are currently being used in commercial portable power tools). In addition, the technology is actively being considered for hybrid electric vehicle (HEV) and electric vehicle (EV) applications. In current work, a number of low-temperature electrolytes have been developed based on advances involving lithium hexafluorophosphate-based solutions in carbonate and carbonate + ester solvent blends, which have been further optimized in the context of the technology and targeted applications. The approaches employed, which include the use of ternary mixtures of carbonates, the use of ester co-solvents [e.g., methyl butyrate (MB)], and optimized lithium salt concentrations (e.g., LiPF6), were compared with the commercial baseline electrolyte, as well as an electrolyte being actively considered for DoE HEV applications and previously developed by a commercial enterprise, namely LiPF6 in ethylene carbonate (EC) + ethyl methyl carbonate (EMC)(30:70%).
نوع الوثيقة: other/unknown material
وصف الملف: application/pdf
اللغة: unknown
العلاقة: Document ID: 20100005256; http://hdl.handle.net/2060/20100005256Test
الإتاحة: http://hdl.handle.net/2060/20100005256Test
حقوق: Copyright, Distribution as joint owner in the copyright
رقم الانضمام: edsbas.1A6F308A
قاعدة البيانات: BASE