التفاصيل البيبلوغرافية
| العنوان: |
Size-Dependent Chemomechanical Failure of Sulfide Solid Electrolyte Particles during Electrochemical Reaction with Lithium |
| المؤلفون: |
Zhao, Jun, Zhao, Chao, Zhu, Jianping, Liu, Xiangsi, Yao, Jingming, Wang, Bo, Dai, Qiushi, Wang, Zaifa, Chen, Jingzhao, Jia, Peng, Li, Yanshuai, Harris, Stephen J, Yang, Yong, Tang, Yongfu, Zhang, Liqiang, Ding, Feng, Huang, Jianyu |
| المصدر: |
Nano Letters, vol 22, iss 1 |
| بيانات النشر: |
eScholarship, University of California |
| سنة النشر: |
2022 |
| المجموعة: |
University of California: eScholarship |
| مصطلحات موضوعية: |
Engineering, Materials Engineering, Chemical Sciences, Physical Chemistry, Affordable and Clean Energy, Solid-state batteries, Chemomechanical failure, Size effect, Sulfide solid electrolyte, Nanoscience & Nanotechnology |
| جغرافية الموضوع: |
411 - 418 |
| الوصف: |
The very high ionic conductivity of Li10GeP2S12 (LGPS) solid electrolyte (SE) makes it a promising candidate SE for solid-state batteries in electrical vehicles. However, chemomechanical failure, whose mechanism remains unclear, has plagued its widespread applications. Here, we report in situ imaging lithiation-induced failure of LGPS SE. We revealed a strong size effect in the chemomechanical failure of LGPS particles: namely, when the particle size is greater than 3 μm, fracture/pulverization occurred; when the particle size is between 1 and 3 μm, microcracks emerged; when the particle size is less than 1 μm, no chemomechanical failure was observed. This strong size effect is interpreted by the interplay between elastic energy storage and dissipation. Our finding has important implications for the design of high-performance LGPS SE, for example, by reducing the particle size to less than 1 μm the chemomechanical failure of LGPS SE can be mitigated. |
| نوع الوثيقة: |
article in journal/newspaper |
| وصف الملف: |
application/pdf |
| اللغة: |
unknown |
| العلاقة: |
qt6s62m61q; https://escholarship.org/uc/item/6s62m61qTest |
| الإتاحة: |
https://escholarship.org/uc/item/6s62m61qTest |
| حقوق: |
CC-BY-NC |
| رقم الانضمام: |
edsbas.BDE3091D |
| قاعدة البيانات: |
BASE |
