التفاصيل البيبلوغرافية
العنوان: |
Synthesis of 1,3,6-Trisubstituted Azulenes Based on the 1-Acyloxyazulene Scaffold. |
المؤلفون: |
Leino, Teppo O.1 teppo.leino@helsinki.fi, Johansson, Niklas G.1, Devisscher, Lars1, Sipari, Nina2, Yli‐Kauhaluoma, Jari1, Wallén, Erik A. A.1 |
المصدر: |
European Journal of Organic Chemistry. Nov2016, Vol. 2016 Issue 33, p5539-5544. 6p. |
مصطلحات موضوعية: |
*AZULENE, *CHEMICAL synthesis, *ACYLOXYL radicals, *NAPHTHALENE, *REACTIVE oxygen species |
مستخلص: |
An efficient synthetic route to 1,3,6-trisubstituted azulenes based on the 1-acyloxyazulene scaffold was developed. The 1-position in azulene was substituted in the ring-formation step with a functionalized acyloxy group. Additionally, the 3- and 6-positions of azulene were functionalized with versatile synthetic handles, a halogen atom and a formyl group. [ABSTRACT FROM AUTHOR] |
قاعدة البيانات: |
Academic Search Index |