التفاصيل البيبلوغرافية
| العنوان: |
Palladium supported on metal–organic framework as a catalyst for the hydrogenation of nitroarenes under mild conditions. |
| المؤلفون: |
Bao, Lingxiang, Yu, Zongbao, Fei, Teng, Yan, Zhiyuan, Li, Jiazhe, Sun, Chenghui, Pang, Siping |
| المصدر: |
Applied Organometallic Chemistry; Jun2020, Vol. 34 Issue 6, p1-8, 8p |
| مصطلحات موضوعية: |
METAL-organic frameworks, HYDROGENATION, CATALYTIC hydrogenation, PALLADIUM catalysts, PALLADIUM, CATALYTIC activity |
| مستخلص: |
Sustainable development demands an environmentally friendly and efficient method for the hydrogenation of organic molecules, including the hydrogenation of functionalized nitroarenes. In this study, a highly active and selective metal–organic framework‐supported palladium catalyst was prepared for the catalytic hydrogenation of nitroarenes. High selectivity (>99%) and excellent yield (98%) of aniline were realized after 2 hours in ethanol under hydrogen (1 atm) at room temperature. The reductions were successfully carried out in the presence of a wide range of other reducible functional groups. More importantly, the catalyst was very stable without the loss of its catalytic activity after five cycles. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
