التفاصيل البيبلوغرافية
| العنوان: |
Organocatalytic Enantioselective Aza-Michael Reaction of Benzotriazole to β,β-Disubstituted Nitroalkenes. |
| المؤلفون: |
Chen, Sheng‐Wei1, Zhang, Gui‐Cheng1, Lou, Qin‐Xin1, Cui, Wei1, Zhang, Sha‐Sha1, Hu, Wen‐Hui1 hu_wenhui@gibh.ac.cn, Zhao, Jun‐Ling1 zhao_junling@gibh.ac.cn |
| المصدر: |
ChemCatChem. 7/3/2015, Vol. 7 Issue 13, p1935-1938. 4p. |
| مصطلحات موضوعية: |
*BENZOTRIAZOLE, *NITROALKENES, *ORGANOCATALYSIS, *MICHAEL reaction, *ENANTIOSELECTIVE catalysis |
| مستخلص: |
An enantioselective aza-Michael reaction of benzotriazole to β,β-disubstituted nitroalkenes has been developed. This reaction was catalyzed efficiently by a bifunctional thiourea catalyst, affording the corresponding products, bearing quaternary stereogenic centers, in moderate to high yields (up to 80%) and with high enantioselectivities of up to 95% ee. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
Academic Search Index |
