دورية أكاديمية
In Situ Growth of Ni-MOF Nanorods Array on Ti 3 C 2 T x Nanosheets for Supercapacitive Electrodes
| العنوان: | In Situ Growth of Ni-MOF Nanorods Array on Ti 3 C 2 T x Nanosheets for Supercapacitive Electrodes |
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| المؤلفون: | Shengzhao Li, Yingyi Wang, Yue Li, Jiaqiang Xu, Tie Li, Ting Zhang |
| المصدر: | Nanomaterials, Vol 13, Iss 3, p 610 (2023) |
| بيانات النشر: | MDPI AG |
| سنة النشر: | 2023 |
| المجموعة: | Directory of Open Access Journals: DOAJ Articles |
| مصطلحات موضوعية: | MXene, MOFs, in situ growth, nanorods, supercapacitor, Chemistry, QD1-999 |
| الوصف: | For the energy supply of smart and portable equipment, high performance supercapacitor electrode materials are drawing more and more concerns. Conductive Ni-MOF is a class of materials with higher conductivity compared with traditional MOFs, but it continues to lack stability. Specifically, MXene (Ti 3 C 2 T x ) has been employed as an electrochemical substrate for its high mechanical stability and abundant active sites, which can be combined with MOFs to improve its electrochemical performance. In this paper, a novel Ni-MOF nanorods array/Ti 3 C 2 T x nanocomposite was prepared via a facile hydrothermal reaction, which makes good use of the advantages of conductive Ni-MOF and high strength Ti 3 C 2 T x . The high density forest-like Ni-MOF array in situ grown on the surface of Ti 3 C 2 T x can provide abundant active electrochemical sites and construct a pathway for effective ion transport. The formation of a “Ti-O···Ni” bond accomplished during an in situ growth reaction endows the strong interfacial interaction between Ni-MOF and Ti 3 C 2 T x . As a result, the Ni-MOF/Ti 3 C 2 T x nanocomposite can achieve a high specific capacitance of 497.6 F·g −1 at 0.5 A·g −1 and remain over 66% of the initial capacitance when the current density increases five times. In addition, the influence of the Ti 3 C 2 T x concentration and reaction time on the morphology and performance of the resultant products were also investigated, leading to a good understanding of the formation process of the nanocomposite and the electrochemical mechanism for a supercapacitive reaction. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 2079-4991 |
| العلاقة: | https://www.mdpi.com/2079-4991/13/3/610Test; https://doaj.org/toc/2079-4991Test; https://doaj.org/article/692a61f591da46d3a4aec59868abadaeTest |
| DOI: | 10.3390/nano13030610 |
| الإتاحة: | https://doi.org/10.3390/nano13030610Test https://doaj.org/article/692a61f591da46d3a4aec59868abadaeTest |
| رقم الانضمام: | edsbas.BE4F44B9 |
| قاعدة البيانات: | BASE |
Full Text Finder | تدمد: | 20794991 |
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| DOI: | 10.3390/nano13030610 |