التفاصيل البيبلوغرافية
| العنوان: |
Synthesis and spectroscopic characterisation of a heterodinuclear iron(III)-copper(II) complex based on an asymmetric dinucleating ligand system |
| المؤلفون: |
Florian Heims, Claudio Greco, Stefan Mebs, Antonella Ciancetta, Annie K. Powell, Kallol Ray, Valeriu Mereacre |
| المساهمون: |
Heims, F, Mereacre, V, Ciancetta, A, Mebs, S, Powell, A, Greco, C, Ray, K |
| بيانات النشر: |
Wiley-VCH, 2012. |
| سنة النشر: |
2012 |
| مصطلحات موضوعية: |
Inorganic Chemistry, Asymmetric Dinucleating Ligand System, Crystallography, Chemistry, Metalation, Ligand, Stereochemistry, Theoretical chemistry, chemistry.chemical_element, Chelation, Bioinorganic chemistry, Copper, NO |
| الوصف: |
The site-directed generation of a heterodinuclear Fe IIICu II complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| اللغة: |
English |
| الوصول الحر: |
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a7ab55e262bcfbeb741e6c42e4481471Test
http://hdl.handle.net/10281/45825Test |
| حقوق: |
CLOSED |
| رقم الانضمام: |
edsair.doi.dedup.....a7ab55e262bcfbeb741e6c42e4481471 |
| قاعدة البيانات: |
OpenAIRE |
