التفاصيل البيبلوغرافية
| العنوان: |
Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes. |
| المؤلفون: |
Bidal, Yannick D., Santoro, Orlando, Melaimi, Mohand, Cordes, David B., Slawin, Alexandra M. Z., Bertrand, Guy, Cazin, Catherine S. J. |
| المصدر: |
Chemistry - A European Journal; 6/27/2016, Vol. 22 Issue 27, p9404-9409, 6p |
| مصطلحات موضوعية: |
CARBENES, CATALYSTS, MESOIONIC compounds, TRANSITION metal alloys, TRANSITION metals |
| مستخلص: |
Carbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the CuI-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs ( aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
