يعرض 1 - 10 نتائج من 68 نتيجة بحث عن '"Jie Lian"', وقت الاستعلام: 0.92s تنقيح النتائج
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    المصدر: npj 2D Materials and Applications, Vol 6, Iss 1, Pp 1-8 (2022)

    الوصف: Palladium diselenide (PdSe2), a new type of two-dimensional noble metal dihalides (NMDCs), has received widespread attention for its excellent electrical and optoelectronic properties. Herein, high-quality continuous centimeter-scale PdSe2 films with layers in the range of 3L–15L were grown using Chemical Vapor Deposition (CVD) method. The absorption spectra and DFT calculations revealed that the bandgap of the PdSe2 films decreased with the increasing number of layers, which is due to the enhancement of orbital hybridization. Spectroscopic ellipsometry (SE) analysis shows that PdSe2 has significant layer-dependent optical and dielectric properties. This is mainly due to the unique strong exciton effect of the thin PdSe2 film in the UV band. In particular, the effect of temperature on the optical properties of PdSe2 films was also observed, and the thermo-optical coefficients of PdSe2 films with the different number of layers were calculated. This study provides fundamental guidance for the fabrication and optimization of PdSe2-based optoelectronic devices.

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    المؤلفون: Wen Zhang, Min-jie Lian, Cai-wu Lu, Di Liu

    المصدر: International Journal of Minerals, Metallurgy and Materials. 27:1036-1045

    الوصف: Small-particle interlayers (lenticles) show some characteristic hydraulic properties and can affect the movement of unsaturated water. In this study, we developed a novel online capillary-water-absorption monitoring device and conducted three groups of comparison tests to simulate lenticle positions and thicknesses with respect to the capillary rise. The results show that the characteristic wetting front exhibits a fast rise in the early stage, a slow rise in the middle stage, and stability in the later stage. The motion of the capillary water in the lenticle is mainly transversal, with the upward curve being “flat,” and the longer is “flat,” the longer is the time needed for the water to move. The interlayer can form a capillary stagnation zone with moisture content close to saturation. The high interlayer may form a discontinuous corrugated capillary zone. Thus, when the wetting front reaches the “coarse-grain (lower)-fine-grain (upper)” interface, the “anti-capillary barrier effect” results in more moisture in the upper layer. Thus, when the wetting front of the capillary water reaches the “fine-grain (upper)-coarse-grain (lower)” interface, the “capillary barrier effect” causes the moisture content of the upper tailings to decreases sharply because of the horizontal movement of the water in the fine medium. It is clear that the presence of lenticles can retard the rise of capillary water by storing water.

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    المصدر: Nature Materials. 19:310-316

    الوصف: The US plan for high-level nuclear waste includes the immobilization of long-lived radionuclides in glass or ceramic waste forms in stainless-steel canisters for disposal in deep geological repositories. Here we report that, under simulated repository conditions, corrosion could be significantly accelerated at the interfaces of different barrier materials, which has not been considered in the current safety and performance assessment models. Severe localized corrosion was found at the interfaces between stainless steel and a model nuclear waste glass and between stainless steel and a ceramic waste form. The accelerated corrosion can be attributed to changes of solution chemistry and local acidity/alkalinity within a confined space, which significantly alter the corrosion of both the waste-form materials and the metallic canisters. The corrosion that is accelerated by the interface interaction between dissimilar materials could profoundly impact the service life of the nuclear waste packages, which, therefore, should be carefully considered when evaluating the performance of waste forms and their packages. Moreover, compatible barriers should be selected to further optimize the performance of the geological repository system. Immobilization of radionuclides in glass or ceramic forms in stainless steel in deep geological repositories is planned in the US for disposal of nuclear waste. Under simulated repository conditions, corrosion could be significantly accelerated at the interfaces of different barrier materials.

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    المصدر: Journal of Alloys and Compounds. 788:891-896

    الوصف: As an accurate technique, spectroscopic ellipsometry (SE) is utilized to study the dielectric function (e = er + iei) of spinel oxide MgTi2O4 (MTO) thin films with good orientation. C-axis lattice length and Ti ions valence state are characterized by X-ray diffraction and X-ray photoelectron spectroscopy, respectively. Here, we find that c-axis lattice constants have the positive correlation with band gaps which are obtained by fitting the spectra of d 2 ( E 2 e i ) / d E 2 via standard critical points model in MTO, and this phenomenon can be revealed by the Ti ions valence state. Moreover, the band gap value of MTO measured by experiment is consistent with the result of first-principles calculations.

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    المساهمون: School of Physical and Mathematical Sciences

    المصدر: MRS Advances. 4:1-7

    الوصف: We use ultrafast coherent two-dimensional electronic spectroscopy (2DES) to study the ultrafast spectral diffusion dynamics of colloidal CdSe quantum dots (QDs) and CdSe nanoplatelets (NPLs). The Center Line Slope (CLS) and Nodal Line Slope (NLS) techniques were employed to analyse the 2DES spectra. We show that no spectral diffusion dynamics occurs for the CdSe QDs. On the other hand, spectral diffusion was observed in the CdSe 5 mono-layers NPLs heavy-hole transition. The normalized Frequency Fluctuation Correlation Function (FFCF) of the CdSe NPLs heavy-hole transition was measured to have a major fast decay component at 140 fs. Ministry of Education (MOE) Accepted version This work is supported by a grant from the Singapore Ministry of Education Tier 2 Academic Research Fund (MOE2015-T2-1-039).

    وصف الملف: application/pdf

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    المصدر: Scripta Materialia. 155:169-174

    الوصف: Advanced microstructure investigations of the high-burnup structure (HBS) in UO2 produced by high-dose 84 MeV Xe ion irradiation are reported. Spark plasma sintered micro-grained UO2 was irradiated to 1357 dpa at 350 °C. The characteristic nano-grains and micro-pores of the HBS were formed. The grain size and grain boundary misorientation distributions of the HBS were measured using transmission electron microscopy based orientation imaging microscopy. Grain polygonization due to accumulation of radiation-induced dislocations was found to be the mechanism of nano-crystallization. The morphology of Xe bubbles was quantitatively investigated. This study provides crucial references for advanced fuel performance modeling of high-burnup UO2.

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    المصدر: Journal of Alloys and Compounds. 756:57-61

    الوصف: Based on the density functional theory (DFT) method, we theoretically studied the novel optical properties of Mg 2-x Ti 1+x O 4 (x = 0, 0.25, 0.5, 0.75) through the first-principles calculations. Electronic structures including bond lengths, band structures and density of states (DOS) were calculated to characterize the optical properties. In fact, Mg 2-x Ti 1+x O 4 's optical properties are dominated by the electronic interband transitions between Ti-3d and O-2p states, and this electronic transition is directly related to the intensity of the Ti-O hybridization. With Mg ions replaced by Ti ions, Mg 2-x Ti 1+x O 4 transfers from insulator to metal, and the Ti-O bond lengths become longer which implies the Ti-O hybridization becomes weaker. As a result, dielectric peaks and absorption peaks both move to the higher energy region (blue shifts) upon the number of substituted Mg ions increasing.