Summary: To realize sustainable development, more and more countries forwarded carbon neutrality goal. Accordingly, improving the utilization efficiency of traditional fossil fuel is an effective strategy for this great goal. Keeping this in mind, developing thermoelectric devices to recover waste heat energy resulted in the consumption process of fuel is demonstrated to be promising. High performance thermoelectric devices require advanced materials. MXenes are a kind of 2D materials with a layered structure, which demonstrate excellent thermoelectric performance owing to their unique physical, mechanical, and chemical properties. Also, substantial achievement has been gained during the past few years in synthesizing MXene based materials for thermoelectric devices. In this review, the mainstream synthetic routes of MXene from etching MAX were summarized. Significantly, the current state and challenges of research on improving the performance of MXene based thermoelectrics are explored, including pristine MXene and MXene based composites.
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