التفاصيل البيبلوغرافية
| العنوان: |
α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping. |
| المؤلفون: |
Seling, Nico, Atobe, Masakazu, Kasten, Kevin, Firth, James D., Karadakov, Peter B., Goldberg, Frederick W., O'Brien, Peter |
| المصدر: |
Angewandte Chemie; 1/8/2024, Vol. 136 Issue 2, p1-6, 6p |
| مصطلحات موضوعية: |
LITHIATION, SULFIDES, ELECTROPHILES, SULFUR, HETEROCYCLIC compounds |
| مستخلص: |
A general and straightforward procedure for the lithiation trapping of cyclic sulfides such as tetrahydrothiophene, tetrahydrothiopyran and a thiomorpholine is described. Trapping with a wide range of electrophiles is demonstrated, leading to more than 50 diverse α‐substituted saturated sulfur heterocycles. The methodology provides access to a range of α‐substituted cyclic sulfides that are not easily synthesised by the currently available methods. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
