التفاصيل البيبلوغرافية
| العنوان: |
Cobalt-Catalyzed Z-Selective Hydrosilylation of Terminal Alkynes. |
| المؤلفون: |
Teo, Wei Jie1, Wang, Chao1, Tan, Ye Wei1, Ge, Shaozhong1 chmgsh@nus.edu.sg |
| المصدر: |
Angewandte Chemie. 4/3/2017, Vol. 129 Issue 15, p4392-4396. 5p. |
| مصطلحات موضوعية: |
*COBALT catalysts, *HYDROSILYLATION, *ALKYNES, *CHEMICAL yield, *PHENOLS |
| مستخلص: |
A cobalt-catalyzed Z-selective hydrosilylation of alkynes has been developed relying on catalysts generated from bench-stable Co(OAc)2 and pyridine-2,6-diimine (PDI) ligands. A variety of functionalized aromatic and aliphatic alkynes undergo this transformation, yielding Z-vinylsilanes in high yields with excellent selectivities ( Z/ E ratio ranges from 90:10 to >99:1). The addition of a catalytic amount of phenol effectively suppressed the Z/ E-isomerization of the Z-vinylsilanes that formed under catalytic conditions. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
Academic Search Index |
