التفاصيل البيبلوغرافية
| العنوان: |
Taming CL-20 through hydrogen bond interaction with nitromethane. |
| المؤلفون: |
Zhang, Wenjin, Bao, Lingxiang, Fei, Teng, Lv, Penghao, Sun, Chenghui, Pang, Siping |
| المصدر: |
CrystEngComm; 12/14/2021, Vol. 23 Issue 46, p8099-8103, 5p |
| مصطلحات موضوعية: |
HYDROGEN bonding interactions, NITROMETHANE, THERMAL stability, HYDROGEN bonding, FURAZANS |
| مستخلص: |
A novel cocrystal explosive comprising CL-20/nitromethane in a 1 : 2 molar ratio was synthesised. Because of the CL-20 molecules were in ε conformation in the cocrystal, they possessed high crystal densities of 1.861 g cm−3 at 153 K and 1.821 g cm−3 at room temperature. Owing to the strong hydrogen bond interaction between the molecules, the decomposition temperature of the cocrystal was found to be 253 °C, which demonstrated excellent thermal stability among the cocrystals of CL-20. In addition, this cocrystal possessed exceptional sensitivities and comparable detonation properties. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
