دورية أكاديمية

Amorphous NiP quantum dots as a robust electrocatalyst for oxygen evolution reaction.

التفاصيل البيبلوغرافية
العنوان: Amorphous NiP quantum dots as a robust electrocatalyst for oxygen evolution reaction.
المؤلفون: Yang, Huijuan1 (AUTHOR), Zhang, Yuling1 (AUTHOR), Xie, Chong1 (AUTHOR), Yan, Cheng1 (AUTHOR), Yi, Xiaoyu1 (AUTHOR), Wang, Chunran1 (AUTHOR), Li, Xifei1 (AUTHOR) xfli@xaut.edu.cn
المصدر: Materials Letters. Oct2022, Vol. 324, pN.PAG-N.PAG. 1p.
مصطلحات موضوعية: *OXYGEN evolution reactions, *ELECTRON configuration, *QUANTUM dots
مستخلص: • 2.7 nm NiP amorphous quantum dots were prepared by metal-support interaction. • Fe/N/C support tunes the NiP quantum dots electron structure configuration. • Overpotential of 242 mV at 10 mA cm−2 and Tafel slopes of 47 mV dec−1 are achieved. Amorphous nickel phosphorus (NiP) is regarded as one of the most promising efficient catalysts for oxygen evolution reaction (OER). Here, amorphous NiP quantum dots with a diameter of 2.7 nm were successfully prepared by metal-Fe/N/C support interaction. Owing to the high specific surface areas, the abundant defects caused by N-doping, and the charge transfer between Fe single atoms and NiP, amorphous NiP quantum dots achieve a low overpotential of 242 mV at 10 mA cm−2. This work provides an efficient way to construct amorphous quantum dots by strong metal-support interaction. [ABSTRACT FROM AUTHOR]
قاعدة البيانات: Academic Search Index
الوصف
تدمد:0167577X
DOI:10.1016/j.matlet.2022.132627