التفاصيل البيبلوغرافية
| العنوان: |
A Trinuclear Iron(III) Complex Containing the Semi-Cubane [Fe(3)(mu(3)-O)](7+) Core: Structural, Spectroscopic, Magnetic and Electrochemical Study |
| المؤلفون: |
Lalia-Kantouri, M., Papadopoulos, C. D., Hatzidimitriou, A. C., Bakas, T., Pachini, S. |
| سنة النشر: |
2010 |
| مصطلحات موضوعية: |
iron, solid-state structures, magnetic properties, electrochemistry, mossbauer spectroscopy, molecular-structures, addition-compounds, crystal, salicylaldehydes, mossbauer, clusters, exchange, behavior, fe |
| الوصف: |
A trinuclear iron(III) oxo-centered complex [Fe(3)(mu(3)-O)(3-OCH(3)-salnec)(3)]OH center dot 5H(2)O was synthesized and characterized as cluster containing the semi-cubane [Fe(3)(mu(3)-O)](7+) core. The central oxygen atom is bridging the three iron(111) ions, which form an equilateral triangle with an average edge of -3.00 angstrom as it was deduced from X-ray diffraction studies. The new tetradentate ligand 3-OCH(3)-salnecH(2) = 1-[1-hydroxy-2(9'-methyl-1,10'-phenanthrolin-2-yl)ethyl]-3-methoxyphenol-2, was generated "in situ" during the synthesis process as a product of the addition reaction between the starting ligands 2,9-dimethyl-phenanthroline(neoc) and 3-methoxy-salicylaldehyde(3-OCH(3)-saloH(2)), in the presence of sodium methoxide and Fe(3+). Variable-temperature magnetic measurements indicate antiferromagnetic exchange interactions between the iron(III) ions in the cluster. Additionally, spectroscopic (IR, UV/Vis, Mossbauer, EPR) and electrochemical studies (CV) are presented and discussed. ; Zeitschrift Fur Anorganische Und Allgemeine Chemie |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| تدمد: |
0044-2313 |
| العلاقة: |
http://olympias.lib.uoi.gr/jspui/handle/123456789/16735Test |
| الإتاحة: |
http://olympias.lib.uoi.gr/jspui/handle/123456789/16735Test |
| حقوق: |
Default Licence ; campus |
| رقم الانضمام: |
edsbas.F5EFC719 |
| قاعدة البيانات: |
BASE |
