دورية أكاديمية

Highly Efficient Green and Red Narrowband Emissive Organic Light‐Emitting Diodes Employing Multi‐Resonant Thermally Activated Delayed Fluorescence Emitters**.

التفاصيل البيبلوغرافية
العنوان: Highly Efficient Green and Red Narrowband Emissive Organic Light‐Emitting Diodes Employing Multi‐Resonant Thermally Activated Delayed Fluorescence Emitters**.
المؤلفون: Wu, Sen, Kumar Gupta, Abhishek, Yoshida, Kou, Gong, Junyi, Hall, David, Cordes, David B., Slawin, Alexandra M. Z., Samuel, Ifor D. W., Zysman‐Colman, Eli
المصدر: Angewandte Chemie; 12/23/2022, Vol. 134 Issue 52, p1-9, 9p
مصطلحات موضوعية: DELAYED fluorescence, LIGHT emitting diodes, ORGANIC light emitting diodes, DIPOLE moments, QUANTUM efficiency
مستخلص: Herein, we demonstrate how judicious selection of the donor decorating a central multi‐resonant thermally activated delayed fluorescence (MR‐TADF) core based on DiKTa can lead to very high‐performance OLEDs. By decorating the DiKTa core with triphenylamine (TPA) and diphenylamine (DPA), 3TPA‐DiKTa and 3DPA‐DiKTa exhibit bright, narrowband green and red emission in doped films, respectively. The OLEDs based on these emitters showed record‐high performance for this family of emitters with maximum external quantum efficiencies (EQEmax) of 30.8 % for 3TPA‐DiKTa at λEL of 551 nm and 16.7 % for 3DPA‐DiKTa at λEL=613 nm. The efficiency roll‐off in the OLEDs was improved significantly by using 4CzIPN as an assistant dopant in hyperfluorescence (HF) devices. The outstanding device performance has been attributed to preferential horizontal orientation of the transition dipole moments of 3TPA‐DiKTa and 3DPA‐DiKTa. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:00448249
DOI:10.1002/ange.202213697