التفاصيل البيبلوغرافية
| العنوان: |
Crystal phase engineering of nanoflower-like hollow MoSe2 boosting polysulfide conversion for lithium–sulfur batteries. |
| المؤلفون: |
Duan, Ruixian, Li, Xifei, Cao, Guiqiang, Chen, Liping, Li, Jun, Jiang, Qinting, Cao, Yanyan, Wang, Jingjing, Li, Wenbin |
| المصدر: |
Nanotechnology; 4/9/2023, Vol. 34 Issue 15, p1-8, 8p |
| مصطلحات موضوعية: |
LITHIUM sulfur batteries, HYDROGEN evolution reactions, OXIDATION-reduction reaction, CRYSTALS, REDUCING agents, CHEMICAL kinetics, CATALYTIC activity |
| مستخلص: |
The battery performance of sulfur cathode has obviously depended on the redox reaction kinetics of polysulfides upon cycling. Herein, an effective strategy was proposed to achieve the conversion from 2H (semiconductor phase) to 1T (metal phase) in hollow nano-flowered molybdenum selenide sphere (HFSMS) through crystal phase engineering. The HFSMS with different phase ratio was realized by regulating the proportion of reducing agents. Specifically, the 1T phase content can reach up to 60.8%, and then subsequently decreased to 59.1% with the further increase of the reducing agent. The as-prepared HFSMS with the 1T phase content of 60.8% showed a smallest Tafel slopes (49.99 and 79.65 mV/dec in reduction and oxidation process, respectively), fastest response time and highest response current (520 s, 0.459 mA in Li2S deposition test), which further exhibited excellent catalytic activity and faster reaction kinetics. This result was verified by electrochemical performance, which manifested as stable cycle life with only 0.112% capacity decay per cycle. It was found that the hollow structure can ensures a rich sulfur storage space, and effectually buffer the volume changes of the active substance. More importantly, the improved performance is attributed to the introduction of the 1T phase, which significantly improves the catalytic activity of MoSe2 with promoting the polysulfide conversion. [ABSTRACT FROM AUTHOR] |
|
Copyright of Nanotechnology is the property of IOP Publishing and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
