دورية أكاديمية

ATOMIC HYDROGEN-DRIVEN SIZE CONTROL OF CATALYTIC NANOPARTICLES FOR SINGLE-WALLED CARBON NANOTUBE GROWTH

التفاصيل البيبلوغرافية
العنوان: ATOMIC HYDROGEN-DRIVEN SIZE CONTROL OF CATALYTIC NANOPARTICLES FOR SINGLE-WALLED CARBON NANOTUBE GROWTH
المؤلفون: Jeong, Hee J., Eude, Laurent, Gowtham, M., Marquardt, Bernd, Lim, Sung H., Enouz, Shaima M., Cojocaru, Costel Sorin, Park, K.A., Lee, Young Hee, Pribat, Didier
المساهمون: Laboratoire de physique des interfaces et des couches minces Palaiseau (LPICM), École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS), NanoMaDe, École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS)-École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS), Department of Energy Science, Sungkyunkwan University Suwon (SKKU)
المصدر: ISSN: 1793-2920.
بيانات النشر: HAL CCSD
World Scientific Publishing
سنة النشر: 2008
المجموعة: École Polytechnique, Université Paris-Saclay: HAL
مصطلحات موضوعية: Single-walled carbon nanotube, atomic hydrogen, catalytic nanoparticle, chemical vapor deposition, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]
الوصف: International audience ; The effects of an atomic hydrogen (Hat ) pretreatment of the catalyst layer on the low tem- perature growth of single-walled carbon nanotubes (SWCNTs) have been investigated using a modified catalytic chemical vapor deposition system. Well-defined and isolated individual Fe nanoparticles as a catalyst are successfully formed on the defects with high trapping energy which are created on the Al2O3 surface by Hat pretreatment, yielding highly dense SWCNTs. The pretreatment mechanism of Hat , compared to H2 , is also discussed. It was also found that the quality of SWCNTs can be enhanced when Hat is flowed with CH4 during nanotubes growth at low temperature. In this case, the undesired carbon products and defects on catalyst seeds and nanotube walls can be selectively removed by Hat . Therefore it is essential to use Hat in the pretreatment stage for increasing catalytic activity and to keep the size of nanoparticles in the nm range. Hat can also be employed in growth stage for enhancing SWCNTs quality and density at low temperature.
نوع الوثيقة: article in journal/newspaper
اللغة: English
العلاقة: hal-00795000; https://hal.science/hal-00795000Test; https://hal.science/hal-00795000/documentTest; https://hal.science/hal-00795000/file/2008-Nano-ATOMIC_HYDROGEN-DRIVEN_SIZE.pdfTest
DOI: 10.1142/S1793292008000939
الإتاحة: https://doi.org/10.1142/S1793292008000939Test
https://hal.science/hal-00795000Test
https://hal.science/hal-00795000/documentTest
https://hal.science/hal-00795000/file/2008-Nano-ATOMIC_HYDROGEN-DRIVEN_SIZE.pdfTest
حقوق: info:eu-repo/semantics/OpenAccess
رقم الانضمام: edsbas.B46B149C
قاعدة البيانات: BASE