Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral Catalysis
| العنوان: | Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral Catalysis |
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| المؤلفون: | Xianhui Bu, Pingyun Feng, Shu-Mei Chen, Jian Zhang, Tao Wu |
| المصدر: | Journal of the American Chemical Society. 130:12882-12883 |
| بيانات النشر: | American Chemical Society (ACS), 2008. |
| سنة النشر: | 2008 |
| مصطلحات موضوعية: | Models, Molecular, Pore size, Cinchona Alkaloids, Thiophenes, Indium, Biochemistry, Article, Catalysis, law.invention, Colloid and Surface Chemistry, law, Organometallic Compounds, Organic chemistry, heterocyclic compounds, Crystallization, Porosity, Chemistry, organic chemicals, technology, industry, and agriculture, Dimethylformamide, Stereoisomerism, General Chemistry, Microporous material, Chemical engineering, Solvents, Induction effect, Chirality (chemistry), Dimethylamines |
| الوصف: | While it is not uncommon to form chiral crystals during crystallization, the formation of bulk porous homochiral materials from achiral building units is rare. Reported here is the homochiral crystallization of microporous materials through the chirality induction effect of natural alkaloids. The resulting material possesses permanent microporosity and has a uniform pore size of 9.3 A. |
| تدمد: | 1520-5126 0002-7863 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::636c007cf6e53becfbb0a31776c0e2c7Test https://doi.org/10.1021/ja805272jTest |
| حقوق: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....636c007cf6e53becfbb0a31776c0e2c7 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15205126 00027863 |
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