التفاصيل البيبلوغرافية
| العنوان: |
Polyoxometalate tri-supported transition metal complexes containing mixed-valent transition metal ions. |
| المؤلفون: |
Fu, Li-Wei, Xiao, Li-Na, Guo, Hai-Yang, Hu, Yang-Yang, Guo, Lan-Lan, Yu, Miao, Cui, Xiao-Bing, Xu, Ji-Qing |
| المصدر: |
Journal of Coordination Chemistry; Nov2015, Vol. 68 Issue 21, p3814-3824, 11p, 3 Color Photographs, 2 Charts |
| مصطلحات موضوعية: |
POLYOXOMETALATES, TRANSITION metal complexes, COMPLEX compounds synthesis, TRANSITION metal ions, ARSENIC compounds, HYDROTHERMAL synthesis, X-ray diffraction |
| مستخلص: |
Three compounds, [AsMo8V6O42][Cu(2,2ʹ-bpy)2]2[Cu(2,2ʹ-bpy)]·4H2O (1), [PMo8V6O42][Cu(2,2ʹ-bpy)2]2[Cu(2,2ʹ-bpy)]·3H2O (2) and [PMo8V6O42][Cu(2,2ʹ-bpy)2]2[Cu(2,2ʹ-bpy)]·3.5H2O (3), have been synthesized under hydrothermal conditions and characterized by IR, UV–vis, XRD, TG, elemental analysis, and X-ray diffraction analysis. Single-crystal X-ray structure analysis reveals that1and2are isostructural and isomorphous, whereas2and3are polymorphs. Polymorphs of1have not been synthesized yet. The mixed-valent transition metal ion in1–3has been further confirmed by TG analyses. Catalytic properties of1and2have also been studied. [ABSTRACT FROM PUBLISHER] |
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| قاعدة البيانات: |
Complementary Index |
