Fluoride-selective optical sensor based on the dipyrrolyl-tetrathiafulvalene chromophore
| العنوان: | Fluoride-selective optical sensor based on the dipyrrolyl-tetrathiafulvalene chromophore |
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| المؤلفون: | Steven J. Langford, Ellen F. Reid, Shadi Rivadehi, Sheshanath V. Bhosale, Conor F. Hogan |
| المصدر: | Org. Biomol. Chem.. 10:705-709 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2012. |
| سنة النشر: | 2012 |
| مصطلحات موضوعية: | Anions, Models, Molecular, Organic Chemistry, Inorganic chemistry, Water, Chromophore, Redox sensor, Electrochemistry, Photochemistry, Biochemistry, Redox, Fluorides, chemistry.chemical_compound, Spectrometry, Fluorescence, chemistry, Heterocyclic Compounds, Spectrophotometry, Pyrroles, Physical and Theoretical Chemistry, Oxidation-Reduction, Fluoride, Tetrathiafulvalene |
| الوصف: | A chemosensor bearing dipyrrolyl motifs as recognition sites and a tetrathiafulvalene redox tag has been evaluated as an optical and redox sensor for a series of anions (F(-), Cl(-), Br(-), HSO(4)(-), CH(3)COO(-), and H(2)PO(4)(-)) in DCM solution. The receptor shows specific optical signaling for fluoride but little electrochemical effect in solution. The solid-state performance of the sensor leads to measurable changes in water. Design implications towards better systems based on these results and other examples are discussed. |
| تدمد: | 1477-0539 1477-0520 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::db5702434925f62279cfc7ad0583621aTest https://doi.org/10.1039/c1ob06459bTest |
| رقم الانضمام: | edsair.doi.dedup.....db5702434925f62279cfc7ad0583621a |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14770539 14770520 |
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