دورية أكاديمية

Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor.

التفاصيل البيبلوغرافية
العنوان: Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor.
المؤلفون: Wong, Joanne W. L., Mailman, Aaron, Winter, Stephen M., Robertson, Craig M., Holmberg, Rebecca J., Murugesu, Muralee, Dube, Paul A., Oakley, Richard T.
المصدر: Chemical Communications; 2014, Vol. 50 Issue 7, p785-787, 3p
مصطلحات موضوعية: SUPRAMOLECULAR chemistry, RADICALS (Chemistry), ANTIFERROMAGNETISM, METAMAGNETISM, ANALYTICAL chemistry, BENZENE
مستخلص: Supramolecular CH...π interactions cause a ruffling of the otherwise coplanar ribbon-like arrays of radicals in the structure of the oxobenzene-bridged bisdithiazolyl 1a. The material displays a conductivity σ(300 K) = 6 × 10-3 S cm-1 (Eact = 0.16 eV) and orders antiferromagnetically below 4 K. At applied fields above 1 kOe the material displays metamagnetic behavior. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:13597345
DOI:10.1039/c3cc46686h