دورية أكاديمية

(+)-Pisatin biosynthesis: From (−) enantiomeric intermediates via an achiral 7,2′-dihydroxy-4′,5′-methylenedioxyisoflav-3-ene.

التفاصيل البيبلوغرافية
العنوان: (+)-Pisatin biosynthesis: From (−) enantiomeric intermediates via an achiral 7,2′-dihydroxy-4′,5′-methylenedioxyisoflav-3-ene.
المؤلفون: Celoy, Rhodesia M.1, VanEtten, Hans D.1 vanetten@ag.arizona.edu
المصدر: Phytochemistry. Feb2014, Vol. 98, p120-127. 8p.
مصطلحات موضوعية: *PISATIN, *ENANTIOMERS, *METHYLENE group, *PEAS, *PLANT cells & tissues, *PHYTOALEXINS
مستخلص: Highlights: [•] (+) Pisatin biosynthesis by pea involves (−) enantiomeric intermediates. [•] A cis but not the trans (−) isoflavanol was metabolized by elicited pea tissue. [•] cis (−) Isoflavanol is converted to an achiral isoflavene by isoflavene synthase. [•] Isoflavene synthase was not found in five other phytoalexins producing plants. [•] cis (−) Isoflavanol and an isoflavene are intermediates in (+) pisatin biosynthesis. [Copyright &y& Elsevier]
قاعدة البيانات: Academic Search Index
الوصف
تدمد:00319422
DOI:10.1016/j.phytochem.2013.10.017