دورية أكاديمية
Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes: synthesis and catalytic activity in 'click chemistry'
| العنوان: | Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes: synthesis and catalytic activity in 'click chemistry' |
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| المؤلفون: | Bidal, Yannick D., Lesieur, Mathieu, Melaimi, Mohand, Nahra, Fady, Cordes, David B., Arachchige, Kasun S. Athukorala, Slawin, Alexandra M. Z., Bertrand, Guy, Cazin, Catherine S. J. |
| بيانات النشر: | Wiley - V C H Verlag |
| سنة النشر: | 2015 |
| المجموعة: | The University of Queensland: UQ eSpace |
| مصطلحات موضوعية: | Azide-Alkyne Cycloaddition, Mesoionic Carbenes, Olefin Metathesis, Room-Temperature, Metal-Complexes, Nhc Ligands, Remote, Hydrogenation, Reactivity, Efficient, 1503 Catalysis, 1605 Organic Chemistry |
| الوصف: | The synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC- and triazolylidene-based copper(I) complexes. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 1615-4150 |
| العلاقة: | orcid:0000-0002-2169-2718; DE-FG02-13ER16370; 1098464 |
| الإتاحة: | https://doi.org/10.1002/adsc.201500453Test https://espace.library.uq.edu.au/view/UQ:9b79b24Test |
| رقم الانضمام: | edsbas.B5011FFE |
| قاعدة البيانات: | BASE |
| تدمد: | 16154150 |
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