دورية أكاديمية
Fungi mediated conversion of benzil to benzoin and hydrobenzoin
العنوان: | Fungi mediated conversion of benzil to benzoin and hydrobenzoin |
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المؤلفون: | Demir, AS, Hamamcı, Haluk, Ayhan, P, Duygu, AN, Igdir, AC, Capanoglu, D |
بيانات النشر: | TETRAHEDRON-ASYMMETRY |
سنة النشر: | 2004 |
مصطلحات موضوعية: | Ligand, Cleavage, Auxiliary, Convenient, Reduction, Aryl aldehydes, Hydroxy ketones, Kinetic resolution, Enantioselective synthesis, Asymmetric dihydroxylation |
الوصف: | An enzyme system of four fungi catalyses the reduction of benzil to benzoin, as well as benzoin to hydrobenzoin. Depending on the pH of the medium, both enantiomers of benzoin can be obtained in good yield and high ee starting from benzil via a reduction, as well as from rac-benzoin via a novel deracemization reaction. Starting from benzil, (R)-, (S)- and rac-benzoin only (R,R)-hydrobenzoin was obtained in high ee and chemical yield. |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | unknown |
تدمد: | 0957-4166 |
العلاقة: | Demir A., Hamamci H., Ayhan P., Duygu A., Igdir A., Capanoglu D., "Fungi mediated conversion of benzil to benzoin and hydrobenzoin", TETRAHEDRON-ASYMMETRY, cilt.15, ss.2579-2582, 2004; 2582; 16; 2579; https://hdl.handle.net/11511/30834Test; 15; WOS:000223666600019 |
DOI: | 10.1016/j.tetasy.2004.07.010 |
الإتاحة: | https://doi.org/10.1016/j.tetasy.2004.07.010Test https://hdl.handle.net/11511/30834Test |
حقوق: | Attribution-NonCommercial-NoDerivatives 4.0 International ; http://creativecommons.org/licenses/by-nc-nd/4.0Test/ |
رقم الانضمام: | edsbas.B0EEC57D |
قاعدة البيانات: | BASE |
تدمد: | 09574166 |
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DOI: | 10.1016/j.tetasy.2004.07.010 |