Carbonization and oxidation of metal–organic frameworks based on 1,4-naphthalene dicarboxylates
| العنوان: | Carbonization and oxidation of metal–organic frameworks based on 1,4-naphthalene dicarboxylates |
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| المؤلفون: | Yu Hao Kang, Duraisamy Senthil Raja, Ya Ting Chen, Chia Her Lin, Jiun Jen Chen, Pen Chang Tseng |
| المصدر: | Science and Technology of Advanced Materials Science and Technology of Advanced Materials, Vol 16, Iss 5 (2015) |
| بيانات النشر: | Taylor & Francis, 2015. |
| سنة النشر: | 2015 |
| مصطلحات موضوعية: | Materials science, Scanning electron microscope, lcsh:Biotechnology, Inorganic chemistry, chemistry.chemical_element, nanoporous carbon, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, chemistry.chemical_compound, metal–organic frameworks, lcsh:TP248.13-248.65, lcsh:TA401-492, General Materials Science, Isostructural, Naphthalene, Carbonization, metal oxide nanoparticle, Sorption, 021001 nanoscience & nanotechnology, 0104 chemical sciences, chemistry, Chemical engineering, Transmission electron microscopy, Papers, Metal-organic framework, lcsh:Materials of engineering and construction. Mechanics of materials, 0210 nano-technology, Carbon |
| الوصف: | Three new isostructural metal–organic frameworks (MOFs), [V(OH)(NDC)] (1), [Cr(OH)(NDC)] (2), and [Ga(OH)(NDC)] (3) have been synthesized hydrothermally using 1,4-naphthalene dicarboxylate (NDC) as the linker. These MOFs (1, 2 and 3) have been used as a template for the synthesis of metal-oxide-inserted nanoporous carbon materials. The newly synthesized MOFs and the resulting porous carbon hybrid functional materials have been characterized using powder x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy dispersive x-ray spectroscopic analysis. Results show that compounds 2 and 3 form their respective metal oxide nanoparticles on the surface of the carbon materials during carbonization at 800 °C. The gas sorption properties of the new MOFs and their corresponding carbon frameworks have been reported. |
| اللغة: | English |
| تدمد: | 1878-5514 1468-6996 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::51980383ece1bd16ffc7c3821209a7f3Test http://europepmc.org/articles/PMC5070018Test |
| حقوق: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....51980383ece1bd16ffc7c3821209a7f3 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 18785514 14686996 |
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