التفاصيل البيبلوغرافية
| العنوان: |
The ESR study of the influence of fluorinated alcohols on spin-adducts of phosphoryl radicals with C60 and C70: a change of magnetic resonance parameters and exclusive formation of monoadducts. |
| المؤلفون: |
Tumanskii, B., Bashilov, V., Shaposhnikova, E., Soldovnikov, S., Bubnov, N., Sokolov, V. |
| المصدر: |
Russian Chemical Bulletin; Sep1998, Vol. 47 Issue 9, p1823-1825, 3p |
| مستخلص: |
Complex formation of.C60P(O)(OPri)2 or three isomers of.C70P(O)(OPri)2 with fluorinated alcohols CF3CH2OH ( 1), (CF3)3COH (2), and (CF3)2CHOH ( 3) results in an increase in the hyperfine splitting constants with the31P nucleus by approximately 3–4 G. Only monoadducts are formed when alcohols 1–3 are added to toluene saturated solutions of Hg[P(O)(OPri)2]2 and C60 under photochemical conditions of multi-addition of phosphoryl radicals to C60. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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