دورية أكاديمية

Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex.

التفاصيل البيبلوغرافية
العنوان: Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex.
المؤلفون: Trose, M., Reiß, M., Reiß, F., Anke, F., Spannenberg, A., Boye, S., Lederer, A., Arndt, P., Beweries, T.
المصدر: Dalton Transactions: An International Journal of Inorganic Chemistry; 10/7/2018, Vol. 47 Issue 37, p12858-12862, 5p
مصطلحات موضوعية: ZIRCONOCENES, BORANES, LIGANDS (Chemistry)
مستخلص: The dinuclear zirconocene chloride complex 1 is a highly active precatalyst for the dehydropolymerisation of methylamine borane. Comparison with mononuclear Zr chlorides and related dinuclear complexes suggests that the nature of the bridging motif is essential for the unique reactivity of 1. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:14779226
DOI:10.1039/c8dt03311k