دورية أكاديمية
Nanopatterned conductive polymer films as a Pt, TCO-free counter electrode for low-cost dye-sensitized solar cells
العنوان: | Nanopatterned conductive polymer films as a Pt, TCO-free counter electrode for low-cost dye-sensitized solar cells |
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المؤلفون: | Kwon, Jeong, Ganapathy, Veerappan, Kim, Young Hun, Song, Kyung-Deok, Park, Hong-Gyu, Jun, Yongseok, Yoo, Pil J., Park, Jong Hyeok |
بيانات النشر: | ROYAL SOC CHEMISTRY |
سنة النشر: | 2013 |
المجموعة: | ScholarWorks@UNIST (Ulsan National Institute of Science and Technology) |
مصطلحات موضوعية: | GEL ELECTROLYTE, EFFICIENCY, POLY(3,4-ETHYLENEDIOXYTHIOPHENE), CATALYSTS |
الوصف: | A low-cost nanopatterned highly conductive poly(3,4-ethylenedioxythiophene) (PEDOT) thin film was fabricated on a flexible plastic substrate via a chemical polymerization method combined with a nanoimprinting technique and used as a platinum (Pt), TCO-free counter electrode for dye-sensitized solar cells (DSSCs). The catalytic properties of the nanopatterned PEDOT as the counter electrode in DSSCs were studied using cyclic voltammetry, J-V measurements, impedance spectroscopy, and finite-difference time-domain (FDTD) simulations. The nanopatterned PEDOT counter electrodes exhibit better functionality as a counter electrode for tri-iodide reduction when compared to non-patterned PEDOT-based counter electrodes. The Pt and TCO-free DSSCs with a nanopatterned PEDOT-based counter electrode exhibited a power conversion efficiency of 7.1% under one sunlight illumination (100 mW cm-2), which is comparable to that of conventional DSSCs with standard platinum Pt/FTO paired counter electrodes. The ability to modulate catalytic functionality with changes in nanoscale morphology represents a promising route for developing new counter electrodes of Pt and TCO-free DSSCs. ; close ; 11 ; 6 |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | English |
تدمد: | 2040-3364 |
العلاقة: | NANOSCALE, v.5, no.17, pp.7838 - 7843; https://scholarworks.unist.ac.kr/handle/201301/2690Test; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84881503382Test; 1054; 12247; 2-s2.0-84881503382; 000322958800022 |
DOI: | 10.1039/c3nr01294h |
الإتاحة: | https://doi.org/10.1039/c3nr01294hTest https://scholarworks.unist.ac.kr/handle/201301/2690Test http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84881503382Test |
رقم الانضمام: | edsbas.DA4DCBE9 |
قاعدة البيانات: | BASE |
تدمد: | 20403364 |
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DOI: | 10.1039/c3nr01294h |