دورية أكاديمية

Nanopatterned conductive polymer films as a Pt, TCO-free counter electrode for low-cost dye-sensitized solar cells

التفاصيل البيبلوغرافية
العنوان: Nanopatterned conductive polymer films as a Pt, TCO-free counter electrode for low-cost dye-sensitized solar cells
المؤلفون: Kwon, Jeong, Ganapathy, Veerappan, Kim, Young Hun, Song, Kyung-Deok, Park, Hong-Gyu, Jun, Yongseok, Yoo, Pil J., Park, Jong Hyeok
بيانات النشر: ROYAL SOC CHEMISTRY
سنة النشر: 2013
المجموعة: ScholarWorks@UNIST (Ulsan National Institute of Science and Technology)
مصطلحات موضوعية: GEL ELECTROLYTE, EFFICIENCY, POLY(3,4-ETHYLENEDIOXYTHIOPHENE), CATALYSTS
الوصف: A low-cost nanopatterned highly conductive poly(3,4-ethylenedioxythiophene) (PEDOT) thin film was fabricated on a flexible plastic substrate via a chemical polymerization method combined with a nanoimprinting technique and used as a platinum (Pt), TCO-free counter electrode for dye-sensitized solar cells (DSSCs). The catalytic properties of the nanopatterned PEDOT as the counter electrode in DSSCs were studied using cyclic voltammetry, J-V measurements, impedance spectroscopy, and finite-difference time-domain (FDTD) simulations. The nanopatterned PEDOT counter electrodes exhibit better functionality as a counter electrode for tri-iodide reduction when compared to non-patterned PEDOT-based counter electrodes. The Pt and TCO-free DSSCs with a nanopatterned PEDOT-based counter electrode exhibited a power conversion efficiency of 7.1% under one sunlight illumination (100 mW cm-2), which is comparable to that of conventional DSSCs with standard platinum Pt/FTO paired counter electrodes. The ability to modulate catalytic functionality with changes in nanoscale morphology represents a promising route for developing new counter electrodes of Pt and TCO-free DSSCs. ; close ; 11 ; 6
نوع الوثيقة: article in journal/newspaper
اللغة: English
تدمد: 2040-3364
العلاقة: NANOSCALE, v.5, no.17, pp.7838 - 7843; https://scholarworks.unist.ac.kr/handle/201301/2690Test; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84881503382Test; 1054; 12247; 2-s2.0-84881503382; 000322958800022
DOI: 10.1039/c3nr01294h
الإتاحة: https://doi.org/10.1039/c3nr01294hTest
https://scholarworks.unist.ac.kr/handle/201301/2690Test
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84881503382Test
رقم الانضمام: edsbas.DA4DCBE9
قاعدة البيانات: BASE
الوصف
تدمد:20403364
DOI:10.1039/c3nr01294h