دورية أكاديمية
Defect-controlled formation of triclinic Na2CoP2O7 for 4 V sodium-ion batteries
العنوان: | Defect-controlled formation of triclinic Na2CoP2O7 for 4 V sodium-ion batteries |
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المؤلفون: | Kim, Heejin, Park, Chan Sun, Choi, Jang Wook, Jung, Yousung |
المساهمون: | 최장욱, Choi, Jang Wook |
بيانات النشر: | John Wiley & Sons Ltd. |
سنة النشر: | 2018 |
المجموعة: | Seoul National University: S-Space |
مصطلحات موضوعية: | PYROPHOSPHATE CATHODE, ELECTROCHEMICAL PERFORMANCE, CRYSTAL-STRUCTURES, LITHIUM, ELECTRODE, POLYMORPHS, VOLTAGE, STORAGE, crystal engineering, density functional calculations, nonstoichiometry, polymorphism, sodium-ion batteries |
الوصف: | Simple defects such as sodium deficiencies can induce the selective synthesis of triclinic Na2CoP2O7, providing an increase in energy density of more than 40% compared to the stoichiometric polymorph that is preferentially formed under the commonly used synthesis conditions. Such a significant improvement, which was achieved just by changing the crystal structure, suggests that controlling the polymorphism could be an effective and facile method for developing high-performance electrode materials and that defects can play a remarkable role in this process. ; N ; 1 |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | unknown |
تدمد: | 1433-7851 |
العلاقة: | Angewandte Chemie - International Edition, Vol.55 No.23, pp.6662-6666; 38568; https://hdl.handle.net/10371/164704Test; 000377921300012; 2-s2.0-84981763319 |
DOI: | 10.1002/anie.201601022 |
الإتاحة: | https://doi.org/10.1002/anie.201601022Test https://hdl.handle.net/10371/164704Test |
رقم الانضمام: | edsbas.4B89389E |
قاعدة البيانات: | BASE |
تدمد: | 14337851 |
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DOI: | 10.1002/anie.201601022 |