دورية أكاديمية
Crystal structure of {2,2′-[ethylenebis(nitrilomethanylylidene)]diphenolato-κ4O,N,N′,O′}oxidovanadium(IV) methanol monosolvate
| العنوان: | Crystal structure of {2,2′-[ethylenebis(nitrilomethanylylidene)]diphenolato-κ4O,N,N′,O′}oxidovanadium(IV) methanol monosolvate |
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| المؤلفون: | Rachel E. Hsuan, Jemma E. Hughes, Thomas H. Miller, Nabila Shaikh, Phoebe H. M. Cunningham, Alice E. O'Connor, Jeremiah P. Tidey, Alexander J. Blake |
| المصدر: | Acta Crystallographica Section E, Vol 70, Iss 11, Pp m380-m381 (2014) |
| بيانات النشر: | International Union of Crystallography, 2014. |
| سنة النشر: | 2014 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | crystal structure, oxidovanadium(IV), 2,2′-[ethylenebis(nitrilomethanylylidene)]diphenolate, N,N′-bis(salicylidene)ethylenediamine, hydrogen bonding, Crystallography, QD901-999 |
| الوصف: | Two independent molecules of the title solvated complex, [V(C16H14N2O2)O]·CH3OH, also known as [N,N′-bis(salicylidene)ethylenediamine]oxidovanadium(IV) or vanadyl salen, crystallize in the asymmetric unit. Each disordered methanol solvent molecule [occupancy ratios 0.678 (4):0.322 (4) and 0.750 (5):0.250 (5)] is linked to a [N,N′-bis(salicylidene)ethylenediamine]oxidovanadium(IV) molecule by an O—H...O hydrogen bond and to others by C—H...O hydrogen bonds. The resulting extended structure consists of a bilayer of molecules parallel to the ab plane. Despite the fact that solvates are common in complexes derived from substituted analogues of the N,N′-bis(salicylidene)ethylenediamine ligand, the title solvate is the first one of [N,N′-bis(salicylidene)ethylenediamine]oxidovanadium(IV) to be structurally characterized. The two vanadyl species have very similar internal geometries, which are best characterized as distorted square-based pyramidal with the vanadium atom displaced from the N2O2 basal plane by 0.5966 (9) Å in the direction of the doubly-bonded oxide ligand. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1600-5368 16005368 |
| العلاقة: | http://scripts.iucr.org/cgi-bin/paper?S1600536814023332Test; https://doaj.org/toc/1600-5368Test |
| DOI: | 10.1107/S1600536814023332 |
| الوصول الحر: | https://doaj.org/article/9b21b2d51c4e4ba59018f6871b3cd10bTest |
| رقم الانضمام: | edsdoj.9b21b2d51c4e4ba59018f6871b3cd10b |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16005368 |
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| DOI: | 10.1107/S1600536814023332 |