Solubility measurement of hydrogen, ethylene, and 1-hexene in polyethylene films through an intelligent gravimetric analyzer
| العنوان: | Solubility measurement of hydrogen, ethylene, and 1-hexene in polyethylene films through an intelligent gravimetric analyzer |
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| المؤلفون: | Wang Haotong, Meijuan Chen, Congjing Ren, Jingyuan Sun, Jian Ye, Jingdai Wang, Binbo Jiang, Yongrong Yang |
| المساهمون: | College of Chemical and Biological Engineering, State Key Laboratory of Chemical Engineering, Zhejiang University, School of Engineering and Digital Arts, University of Kent, Petrochemical Engineering Department, China HuanQiu Contracting and Engineering Corporation, UMR 1010 Chimie Agro-Industrielle, Institut National de la Recherche Agronomique (INRA), Ecole Nationale Supérieure des Ingénieurs en Arts Chimiques et Technologiques, Shanghai Key Laboratory of Catalysis Technology for Polyolefins, National Natural Science Foundation of China [91434205], China Postdoctoral Science Foundation [2014M550327], National Science Fund for Distinguished Young [21525627], Natural Science Foundation of Zhejiang Province [LR14B060001], Specialized Research Fund for the Doctoral Program of Higher Education of China [20130101110063], University of Kent [Canterbury], Chimie Agro-Industrielle (CAI), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole nationale supérieure des ingénieurs en arts chimiques et technologiques-Institut National de la Recherche Agronomique (INRA) |
| المصدر: | Journal of Applied Polymer Science Journal of Applied Polymer Science, Wiley, 2017, 134 (8), 7 p. ⟨10.1002/app.44507⟩ |
| بيانات النشر: | HAL CCSD, 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | Materials science, Polymers and Plastics, Hydrogen, Analytical chemistry, chemistry.chemical_element, gravimétrie, 02 engineering and technology, 010402 general chemistry, gravimetry, 01 natural sciences, chemistry.chemical_compound, Crystallinity, [CHIM.GENI]Chemical Sciences/Chemical engineering, structure-property relationships, Polymer chemistry, Materials Chemistry, Solubility, Sorption, General Chemistry, polyolefine, Atmospheric temperature range, Polyethylene, hydrogène, 021001 nanoscience & nanotechnology, 0104 chemical sciences, Surfaces, Coatings and Films, 1-Hexene, relation structure propriété, chemistry, property structure relationship, éthylène, adsorption, hydrogen, solubilité, Gravimetric analysis, 0210 nano-technology, polyolefins |
| الوصف: | The solubility of hydrogen (H2), ethylene (C2H4), 1-hexene (C6H12), and the mixture of C2H4/1-C6H12 in semicrystalline polyethylene (PE) films is measured using an intelligent gravimetric analyzer (IGA) in combination with prediction equations. For the pure-component sorption in PE, the solubility of C2H4 and 1-C6H12 decreases with the temperature, while that of H2 exhibits an opposite variation tendency in the temperature range under test. For the C2H4/1-C6H12 mixture, the co-solubility is almost 10% smaller than the sum of the pure-component solubility. 1-C6H12 acts as a co-solvent and C2H4 an antisolvent. Moreover, good consistency has been achieved between the measured data and the prediction results from the Sanchez-Lacombe EOS model, demonstrating the reliability of the measurement approach employed in this work. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 134, 44507. |
| اللغة: | English |
| تدمد: | 0021-8995 1097-4628 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b7665b17eabc40fac0aab8a76c507098Test https://hal.archives-ouvertes.fr/hal-01594978Test |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....b7665b17eabc40fac0aab8a76c507098 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 00218995 10974628 |
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