دورية أكاديمية
Bioderived silicon nano-quills: synthesis, structure and performance in lithium-ion battery anodes
| العنوان: | Bioderived silicon nano-quills: synthesis, structure and performance in lithium-ion battery anodes |
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| المؤلفون: | Chen, Nancy, Sabet, Morteza, Sapkota, Nawraj, Parekh, Mihir, Chiluwal, Shailendra, Koehler, Kelliann, Clemons, Craig M., Ding, Yi, Rao, Apparao M., Pilla, Srikanth |
| بيانات النشر: | Green Chemistry |
| سنة النشر: | 2024 |
| المجموعة: | The University of Delaware Library Institutional Repository |
| الوصف: | This article was originally published in Green Chemistry. The version of record is available at: https://doi.org/10.1039/D4GC00498ATest. © The Royal Society of Chemistry 2024 ; Cellulose nanocrystals (CNCs) are bioderived one-dimensional species with versatile surface chemistry and unique self-assembling behavior in aqueous solutions. This work presents a scientific approach to leverage these characteristics for creating CNC network templates and processing them to engineer a novel silicon (Si)-based material called silicon nano-quill (SiNQ) for energy storage applications. The SiNQ structure possesses a porous, tubular morphology with a substantial ability to store lithium ions while maintaining its structural integrity. The presence of Si suboxides in the SiNQ structure is demonstrated to be crucial for realizing a stable cycling performance. One of the defining attributes of SiNQ is its water dispersibility due to Si–H surface bonds, promoting water-based Si-graphite electrode manufacturing with environmental and economic benefits. The incorporation of only 17 wt% SiNQ enhances the capacity of graphitic anodes by ∼2.5 times. An initial coulombic efficiency of 97.5% is achieved by employing a versatile pre-lithiation. The SiNQ-graphite anodes with high active loading, when subjected to accelerated charging/discharging conditions at 5.4 mA cm−2, exhibit stable cycling stability up to 500 cycles and average coulombic efficiency of >99%. A generalized physics-based cyclic voltammetry model is presented to explain the remarkable behavior of SiNQs under fast-charging conditions. ; This work was supported by the US Endowment for Forestry and Communities [Contract No. 20-00082] to synthesize and characterize silicon nano-quills (SiNQs) described in this study. The authors also acknowledge financial support through Clemson University's Virtual Prototyping of Autonomy Enabled Ground Systems (VIPR-GS), under Cooperative Agreement W56HZV-21-2-0001 with the US Army DEVCOM Ground Vehicle Systems Center (GVSC), to develop ... |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| تدمد: | 1463-9270 |
| العلاقة: | Chen, Nancy, Morteza Sabet, Nawraj Sapkota, Mihir Parekh, Shailendra Chiluwal, Kelliann Koehler, Craig M. Clemons, Yi Ding, Apparao M. Rao, and Srikanth Pilla. “Bioderived Silicon Nano-Quills: Synthesis, Structure and Performance in Lithium-Ion Battery Anodes.” Green Chemistry 26, no. 8 (2024): 4691–4702. https://doi.org/10.1039/D4GC00498ATest.; https://udspace.udel.edu/handle/19716/34337Test |
| الإتاحة: | https://doi.org/10.1039/D4GC00498ATest https://udspace.udel.edu/handle/19716/34337Test |
| حقوق: | Attribution-NonCommercial 3.0 Unported ; http://creativecommons.org/licenses/by-nc/3.0Test/ |
| رقم الانضمام: | edsbas.A446A204 |
| قاعدة البيانات: | BASE |
| تدمد: | 14639270 |
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