التفاصيل البيبلوغرافية
| العنوان: |
One-Pot Reaction To Form Hydrophosphorylated Fullerenes from C60 and Ph3-nPCln/ROH. |
| المؤلفون: |
Nana Xin, Xiuying Xie, Chang-Qiu Zhao, Xianqiang Huang, Junhong Zhang, Ji-Yuan Du, Jie Yang, Chun-Lin Ma |
| المصدر: |
Synlett; 2018, Vol. 29 Issue 9, p1219-1222, 4p |
| مصطلحات موضوعية: |
PHOSPHORYLATION, FULLERENE derivatives, REACTIVITY (Chemistry) |
| مستخلص: |
Hydrophosphorylated fullerene derivatives were readily prepared in one step by treating C60 with Ph3-nPCln (n = 1-3) and ROH (R = H, alkyl). The one-pot reaction could be performed under mild conditions with moderate to good yields. Dichlorophenylphosphine and alcohols exhibited unexpected reactivity towards C60. A possible reaction mechanism involving the formation of P(III)-OH in situ was proposed to explain the experimental results. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
