Recent Developments in Cobalt Catalyzed Carbon–Carbon and Carbon–Heteroatom Bond Formation via C–H Bond Functionalization
| العنوان: | Recent Developments in Cobalt Catalyzed Carbon–Carbon and Carbon–Heteroatom Bond Formation via C–H Bond Functionalization |
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| المؤلفون: | Yao-Yu Wang, Muhammad Usman, Zheng-Hui Guan, Zhi-Hui Ren |
| المصدر: | Synthesis. 49:1419-1443 |
| بيانات النشر: | Georg Thieme Verlag KG, 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | 010405 organic chemistry, Electrophilic addition, Organic Chemistry, Heteroatom, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, Combinatorial chemistry, Chemical synthesis, Catalysis, 0104 chemical sciences, chemistry.chemical_compound, chemistry, Organic chemistry, Surface modification, Organic synthesis, Cobalt, Carbon |
| الوصف: | Cobalt catalysts have evolved to be seen as versatile eco-compatible and economical catalysts in organic synthesis in recent years. Cobalt-catalyzed reactions are undoubtedly a classic in synthetic chemistry for the formation of carbon–carbon and carbon–heteroatom bonds. Another important aspect in this field is catalyst variants, such as low-valent and high-valent cobalt catalysts. This review summarizes the recent progress and synthetic utility of low-valent and high-valent cobalt catalysts towards C–H functionalization processes achieving C–C, C–O, C–N and C–B bond formation. Mechanistic insight is also discussed, with the goal of serving as a stepping stone for further development in this field. In addition, Csp3–H bond functionalization reactions provide many opportunities for novel synthesis approaches. 1 Introduction 2 Carbon–Carbon Bond Formation 2.1 Csp2–Csp3 Bond Formation 2.2 Csp2–Csp2 Bond Formation 3 Carbon–Nitrogen Bond Formation 4 Csp3–H Bond Functionalization 5 Carbon–Oxygen Bond Formation 6 Carbon–Boron Bond Formation 7 Conclusion |
| تدمد: | 1437-210X 0039-7881 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::bf4354a50eb189c78e08f14fe9890dc7Test https://doi.org/10.1055/s-0036-1589478Test |
| رقم الانضمام: | edsair.doi...........bf4354a50eb189c78e08f14fe9890dc7 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1437210X 00397881 |
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