The almost lithophile character of nitrogen during core formation
العنوان: | The almost lithophile character of nitrogen during core formation |
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المؤلفون: | Iris M. Speelmanns, Christian Liebske, Max W. Schmidt |
المصدر: | Earth and Planetary Science Letters, 510 |
بيانات النشر: | ETH Zurich, 2019. |
سنة النشر: | 2019 |
مصطلحات موضوعية: | core–mantle differentiation, atmosphere loss, 010504 meteorology & atmospheric sciences, Analytical chemistry, chemistry.chemical_element, 010502 geochemistry & geophysics, Earth accretion, 01 natural sciences, Oxygen, Atmosphere, chemistry.chemical_compound, Geochemistry and Petrology, Mineral redox buffer, Earth and Planetary Sciences (miscellaneous), 0105 earth and related environmental sciences, Accretion (meteorology), Nitrogen, Silicate, Geophysics, chemistry, Space and Planetary Science, nitrogen partitioning, Lithophile, Geology, Earth (classical element) |
الوصف: | Nitrogen is a key constituent of our atmosphere and forms the basis of life, but its early distribution between Earth reservoirs is not well constrained. We investigate nitrogen partitioning between metal and silicate melts over a wide range of conditions relevant for core segregation during Earth accretion, i.e. 1250–2000 °C, 1.5–5.5 GPa and oxygen fugacities of ΔIW-5.9 to ΔIW-1.4 (in log units relative to the iron–wüstite buffer). At 1250 °C, 1.5 GPa, DN metal melt/silicate melt ranges from 14 ± 0.1 at ΔIW-1.4 to 2.0 ± 0.2 at ΔIW-5, N partitioning into the core forming metal. Increasing pressure has no effect on DN metal melt/silicate melt, while increasing temperature dramatically lowers DN metal melt/silicate melt to 0.5 ± 0.15 at ΔIW-4. During early core formation N was hence mildly incompatible in the metal. The partitioning data are then parameterised as a function of temperature and oxygen fugacity and used to model the evolution of N within the two early prevailing reservoirs: the silicate magma ocean and the core. Depending on the oxidation state during accretion, N either behaves lithophile or siderophile. For the most widely favoured initially reduced Earth accretion scenario, N behaves lithophile with a bulk partition coefficient of 0.17 to 1.4, leading to 500–700 ppm N in closed-system core formation models. However, core formation from a magma ocean is very likely accompanied by magma ocean degassing, the core would thus contain ≤100 ppm of N, and hence, does not constitute the missing N reservoir. Bulk Earth N would thus be 34–180 ppm in the absence of other suitable reservoirs, >98% N of the chondritic N have hence been lost during accretion. Earth and Planetary Science Letters, 510 ISSN:0012-821X ISSN:1385-013X |
وصف الملف: | application/application/pdf |
اللغة: | English |
تدمد: | 0012-821X 1385-013X |
DOI: | 10.3929/ethz-b-000320615 |
الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d57f7152b67215c157f1317d9d339189Test |
حقوق: | OPEN |
رقم الانضمام: | edsair.doi.dedup.....d57f7152b67215c157f1317d9d339189 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 0012821X 1385013X |
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DOI: | 10.3929/ethz-b-000320615 |