دورية أكاديمية

Evaluation of disinfection by-products formation during chlorination and chloramination of dissolved natural organic matter fractions isolated from a filtered river water

التفاصيل البيبلوغرافية
العنوان: Evaluation of disinfection by-products formation during chlorination and chloramination of dissolved natural organic matter fractions isolated from a filtered river water
المؤلفون: Lu, Jinfeng1 Jinfeng.Lu.HIT@gmail.com, Zhang, Tao1,2, Ma, Jun1 majun@hit.edu.cn, Chen, Zhonglin1
المصدر: Journal of Hazardous Materials. Feb2009, Vol. 162 Issue 1, p140-145. 6p.
مصطلحات موضوعية: *DISINFECTION by-product, *CHLORINATION, *WATER chloramination, *DISSOLVED organic matter, *TRIHALOMETHANES, *ACETIC acid, *ABSORBANCE scale (Spectroscopy), *STREAM chemistry
مستخلص: Abstract: Dissolved natural organic matter (DOM) in a filtered river water was isolated and fractionated into six different fractions. Trihalomethanes (THMs) and haloacetic acids (HAAs) formed from these isolated DOM fractions during chlorination and chloramination were determined. Results show that the hydrophobic acid, hydrophilic acid, hydrophilic base and hydrophobic neutral are major precursors of THMs and HAAs. There exist good correlations between the values of specific ultraviolet absorbance at 254nm of the individual DOM fractions and their disinfection by-products formation potential, indicating that aromatic moieties are responsible for disinfection by-products formation for both hydrophobic and hydrophilic DOM fractions. Chloramination of the DOM fractions yields much less THMs and HAAs than chlorination. For the dominant DOM fraction (i.e. hydrophobic acid) in the water, the yields of THMs and HAAs increase more significantly in chlorination than those in chloramination with the increase of disinfectant dosage, contact time and dissolved organic carbon content. [Copyright &y& Elsevier]
قاعدة البيانات: Academic Search Index
الوصف
تدمد:03043894
DOI:10.1016/j.jhazmat.2008.05.058